Efficient method for the synthesis of 1,3-unsubstituted 2-imino-5-oxooctahydroimidazo[4,5-d]imidazolium iodides based on thioglycolurils

被引：5

作者：

Baranov, Vladimir V. ^{[1
]}

Yatsenko, Evgeniya L. ^{[1
,2
]}

Melnikova, Elizaveta K. ^{[3
,4
]}

Nelyubina, Yulia V. ^{[3
]}

Kravchenko, Angelina N. ^{[1
]}

机构：

[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, 47 Leninsky Ave, Moscow 119991, Russia

[2] DI Mendeleev Univ Chem Technol Russia, 9 Miusskaya Sq, Moscow 125047, Russia

[3] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, 28 Vavilova St, Moscow 119991, Russia

[4] Moscow MV Lomonosov State Univ, 1-3 Leninskie Gory, Moscow 119991, Russia

来源：

CHEMISTRY OF HETEROCYCLIC COMPOUNDS | 2019年 / 55卷 / 02期

基金：

俄罗斯科学基金会;

关键词：

iminoglycolurils; isothiouronium salts; thioglycolurils; condensation; S-methylation;

D O I：

10.1007/s10593-019-02433-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A facile and efficient two-step synthetic route to previously inaccessible 1,3-unsubstituted 2-imino-5-oxooctahydroimidazo[4,5-d]-imidazol-1-ium iodides has been developed using easily accessible thioglycolurils, MeI, and various primary amines, morpholine, or ethylene diamine. The structure of representative products and hydrogen-bonding pattern in their crystals have been investigated by X-ray diffraction.

引用

页码：160 / 166

页数：7

共 17 条

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