Superhydrophobic Conducting Polyaniline Prepared via Interfacial Polymerization

被引：6

作者：

Wang Liang ^{[1
]}

Ding Chun-Mei ^{[1
]}

Zhu Ying ^{[1
]}

Wan Mei-Xiang ^{[2
]}

Jiang Lei ^{[1
,2
]}

机构：

[1] Beijing Univ Aeronaut & Astronaut, Sch Chem & Environm, Minist Educ, Key Lab Bioinspired Smart Interfacial Sci & Techn, Beijing 100191, Peoples R China

[2] Chinese Acad Sci, Inst Chem, Key Lab Organ Solids, Beijing 100190, Peoples R China

来源：

CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 2012年 / 33卷 / 06期

关键词：

Conducting polyaniline; Interfacial polymerization; Three-dimensional micro/nanostructure; Superhydrophobicity; NANOFIBERS; WETTABILITY; MICROSTRUCTURES; NANOSTRUCTURES; SURFACES;

D O I：

10.3969/j.issn.0251-0790.2012.06.039

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three-dimensional(3D) micro/nanostructures of polyaniline(PANT) were self-assembled by template-free method combined with interfacial polymerization in the presence of perfluorosebacic acid(PFSEA) as dopant. The 3D micro/nanostructures of PANT show both electrical conductivity and superhydrophobicity. It was proposed that the aniline filled hi-layer micelles composed of PFSEA/An salt were served as the soft-templates of the self-assembled nanofibers, then those nanofibers were self-assembled to form 3D-microstructures by the intermolecular interactions including hydrogen bonding and hydrophobic interaction as the driving forces. Moreover, their morphology and size can be controlled by changing the concentration and the molar ratio of aniline and oxidant. The method is a facile approach to prepare conducting polymer 3D architectures assembled by 1D-nanostructure.

引用

页码：1355 / 1359

页数：5

共 18 条

[1] ASTURIAS GE, 1989, SYNTHETIC MET, V29, P157
[2] Wettability of porous surfaces.
Cassie, ABD
Baxter, S
[J]. TRANSACTIONS OF THE FARADAY SOCIETY, 1944, 40 : 0546 - 0550
[3] CEPAK VM, 1999, CHEM MATER, V11, P1183
[4] Du CG, 2010, CHEM J CHINESE U, V31, P421
[5] Polyaniline nanofibers: Facile synthesis and chemical sensors
Huang, JX
Virji, S
Weiller, BH
Kaner, RB
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (02) : 314 - 315
[6] Shape and aggregation control of nanoparticles: Not shaken, not stirred
Department of Chemistry and Biochemistry, California NanoSystems Institute, University of California, Los Angeles, Los Angeles, CA 90095-1569, United States
[J]. J. Am. Chem. Soc., 2006, 3 (968-975):
[7] THE CONCEPT OF SECONDARY DOPING AS APPLIED TO POLYANILINE
MACDIARMID, AG
EPSTEIN, AJ
[J]. SYNTHETIC METALS, 1994, 65 (2-3) : 103 - 116
[8] POLYANILINE - INTERCONVERSION OF METALLIC AND INSULATING FORMS
MACDIARMID, AG
CHIANG, JC
HALPERN, M
HUANG, WS
MU, SL
SOMASIRI, NLD
WU, WQ
YANIGER, SI
[J]. MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1985, 121 (1-4): : 173 - 180
[9] Synthesis of polyaniline nanostructures in different lamellar liquid crystals and application to lubrication
Song, Genping
Han, Jie
Bo, Jie
Guo, Rong
[J]. JOURNAL OF MATERIALS SCIENCE, 2009, 44 (03) : 715 - 720
[10] A template-free method towards conducting polymer nanostructures
Wan, Meixiang
[J]. ADVANCED MATERIALS, 2008, 20 (15) : 2926 - 2932

← 1 2 →