One-dimensional cobalt and zinc complexes involving in situ reaction of ethylenediamine and acetonitrile to form imidazoline ligand
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作者:
Hao, ZM
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Shanxi Normal Univ, Sch Chem & Mat Sci, Linfen 041004, Shanxi, Peoples R ChinaShanxi Normal Univ, Sch Chem & Mat Sci, Linfen 041004, Shanxi, Peoples R China
Hao, ZM
[1
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Zhang, XM
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Shanxi Normal Univ, Sch Chem & Mat Sci, Linfen 041004, Shanxi, Peoples R ChinaShanxi Normal Univ, Sch Chem & Mat Sci, Linfen 041004, Shanxi, Peoples R China
Zhang, XM
[1
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机构:
[1] Shanxi Normal Univ, Sch Chem & Mat Sci, Linfen 041004, Shanxi, Peoples R China
The solvothermal treatment of cobalt nitrate (or zinc acetate), ethylenediamine and dicarboxylate in acetonitrile produced two one-dimensional coordination polymers [Co(mimz)(2)(ox)](n) (1) and [Zn(mimz)(2)(ip)](n) (2) (mimz = 2-methylimidazoline, ox = oxalate, ip = isophthalate) which ligand involving in situ formation of imidazoline ligand by cycloaddition reaction of ethylenediamine and acetonitrile. (c) 2005 Elsevier B.V. All rights reserved.