One-dimensional cobalt and zinc complexes involving in situ reaction of ethylenediamine and acetonitrile to form imidazoline ligand

被引：13

作者：

Hao, ZM ^{[1
]}

Zhang, XM ^{[1
]}

机构：

[1] Shanxi Normal Univ, Sch Chem & Mat Sci, Linfen 041004, Shanxi, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2006年 / 9卷 / 01期

基金：

中国国家自然科学基金;

关键词：

imidazoline; ligand reaction;

D O I：

10.1016/j.inoche.2005.10.007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The solvothermal treatment of cobalt nitrate (or zinc acetate), ethylenediamine and dicarboxylate in acetonitrile produced two one-dimensional coordination polymers [Co(mimz)(2)(ox)](n) (1) and [Zn(mimz)(2)(ip)](n) (2) (mimz = 2-methylimidazoline, ox = oxalate, ip = isophthalate) which ligand involving in situ formation of imidazoline ligand by cycloaddition reaction of ethylenediamine and acetonitrile. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：57 / 59

页数：3

共 20 条

[1]

[Anonymous], COORD CHEM REV

[2]

BOYD GV, 1991, CHEM AMIDINES IMIDAT, V2, P339

[3] Models for arginine-metal binding. Synthesis of guanidine and urea ligands through amination and hydration of a cyanamide ligand bound to platinum(II), osmium(III), and cobalt(III) [J].

Fairlie, DP ;

Jackson, WG ;

Skelton, BW ;

Wen, H ;

White, AH ;

Wickramasinghe, WA ;

Woon, TC ;

Taube, H .

INORGANIC CHEMISTRY, 1997, 36 (06) :1020-1028

[4] USE OF LANTHANIDE(III) IONS AS CATALYSTS FOR THE REACTIONS OF AMINES WITH NITRILES [J].

FORSBERG, JH ;

SPAZIANO, VT ;

BALASUBRAMANIAN, TM ;

LIU, GK ;

KINSLEY, SA ;

DUCKWORTH, CA ;

POTERUCA, JJ ;

BROWN, PS ;

MILLER, JL .

JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (06) :1017-1021

[5] Synthesis and base hydrolysis kinetics of the nitrile complexes [Co(tetren)NCR]3+ (R = Me, Ph and p-MeOC6 H4) and the synthesis and kinetics of formation of the tetrazolato complexes [Co(tetren)N4R]2+ (R = Me and Ph; tetren = 1,11-diamino-3,6,9-triazaundecane) by reaction with azide ion [J].

Hay, RW ;

McLaren, FM .

TRANSITION METAL CHEMISTRY, 1999, 24 (04) :398-402

[6] Formation of two stable seven-membered chelate rings bound to one metal center due to addition of bifunctional amine to coordinated nitriles [J].

Kukushkin, YN ;

Kiseleva, NP ;

Zangrando, E ;

Kukushkin, VY .

INORGANICA CHIMICA ACTA, 1999, 285 (02) :203-207

[7] Thermoanalytical investigation of Ni(II), Co(II) and Cu(II) complexes with imidazole-4-acetic acid [J].

Materazzi, S ;

Vasca, E .

THERMOCHIMICA ACTA, 2001, 373 (01) :7-11

[8] Reactions of transition metal-coordinated nitriles [J].

Michelin, RA ;

Mozzon, M ;

Bertani, R .

COORDINATION CHEMISTRY REVIEWS, 1996, 147 :299-338

[9] REACTIONS OF AZIRIDINE WITH PLATINUM(II) NITRILES - FORMATION OF (AZIRIDINO)AMIDINES AND 2-IMIDAZOLINES AND X-RAY STRUCTURE OF TRANS-[PTCL2(N(H)=C(PH)NCH2CH2)2] [J].

MICHELIN, RA ;

MOZZON, M ;

BERTANI, R ;

BENETOLLO, F ;

BOMBIERI, G ;

ANGELICI, RJ .

INORGANICA CHIMICA ACTA, 1994, 222 (1-2) :327-337

[10] Low-valent ruthenium and iridium hydride complexes as alternatives to Lewis acid and base catalysts [J].

Murahashi, S ;

Takaya, H .

ACCOUNTS OF CHEMICAL RESEARCH, 2000, 33 (04) :225-233

← 1 2 →