The enhanced photoactivity of nanosized Bi2WO6 catalyst for the degradation of 4-chlorophenol

被引:28
作者
Fu, Hongbo [1 ,2 ]
Yao, Wenqing [2 ]
Zhang, Liwu [2 ]
Zhu, Yongfa [2 ]
机构
[1] Fudan Univ, Dept Environm Sci & Engn, Shanghai 200433, Peoples R China
[2] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China
基金
美国国家科学基金会; 中国博士后科学基金;
关键词
nanostructures; semiconductors; surface properties;
D O I
10.1016/j.materresbull.2007.10.044
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Nanosized Bi2WO6 catalyst exhibited the enhanced photoactivity for the degradation of 4-chlorophenol (4-CP) under visible irradiation compared to the sample prepared by high-temperature solid reaction. The photoactivity of the catalyst was sensitive to pH variation of the suspension. Nanosized Bi2WO6 catalyst showed the highest activity at pH 7.2. The photodegradation of 4-CP by nanosized Bi2WO6 catalyst followed a pseudo-first-order reaction. After three recycling runs for the photodegraclation of 4-CP, the activity of the catalyst did not show any significant loss, suggesting that the catalyst was stable under visible irradiation. (C) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2617 / 2625
页数:9
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