11,11,12,12-Tetracyano-9,10-anthraquinodimethane (TCNAQ) derivatives having four types of aryl substituents, phenyl, biphenyl-4-yl, thien-2-yl, and 2,2'-bithiophen-5-yl groups at their 2-position, were synthesized and characterized. Their crystal structures were determined by single-crystal X-ray structure analysis, revealing that the TCNAQ moiety and electron-donating substituents form donor acceptor-segregated columnar structures. The combination of nonplanar electron acceptor TCNAQ and planar donor units provides a good way to afford segregated columnar structures.
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Univ Tokyo, Dept Chem, Grad Sch Sci, Bunkyo Ku, Tokyo 1130033, JapanUniv Tokyo, Dept Chem, Grad Sch Sci, Bunkyo Ku, Tokyo 1130033, Japan
Yoshino, Junro
Furuta, Akiko
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Univ Tokyo, Dept Chem, Grad Sch Sci, Bunkyo Ku, Tokyo 1130033, JapanUniv Tokyo, Dept Chem, Grad Sch Sci, Bunkyo Ku, Tokyo 1130033, Japan
Furuta, Akiko
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Kambe, Tetsuya
Itoi, Hiroaki
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Univ Tokyo, Dept Chem, Grad Sch Sci, Bunkyo Ku, Tokyo 1130033, JapanUniv Tokyo, Dept Chem, Grad Sch Sci, Bunkyo Ku, Tokyo 1130033, Japan
Itoi, Hiroaki
Kano, Naokazu
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Univ Tokyo, Dept Chem, Grad Sch Sci, Bunkyo Ku, Tokyo 1130033, JapanUniv Tokyo, Dept Chem, Grad Sch Sci, Bunkyo Ku, Tokyo 1130033, Japan
Kano, Naokazu
Kawashima, Takayuki
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Univ Tokyo, Dept Chem, Grad Sch Sci, Bunkyo Ku, Tokyo 1130033, JapanUniv Tokyo, Dept Chem, Grad Sch Sci, Bunkyo Ku, Tokyo 1130033, Japan
Kawashima, Takayuki
Ito, Yuzuru
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Natl Inst Adv Ind Sci & Technol, Organ Dev Res Lab, Tsukuba, Ibaraki 3058562, JapanUniv Tokyo, Dept Chem, Grad Sch Sci, Bunkyo Ku, Tokyo 1130033, Japan
Ito, Yuzuru
Asashima, Makoto
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Natl Inst Adv Ind Sci & Technol, Organ Dev Res Lab, Tsukuba, Ibaraki 3058562, Japan
Univ Tokyo, Grad Sch Arts & Sci, Dept Life Sci Biol, Meguro Ku, Tokyo 1538902, JapanUniv Tokyo, Dept Chem, Grad Sch Sci, Bunkyo Ku, Tokyo 1130033, Japan