Tetracyanoanthraquinodimethanes Having Biaryl Substituents: Synthesis, Crystal Structures, and Physical Properties

被引:12
|
作者
Chiba, Hiroshi [1 ]
Nishida, Jun-ichi [1 ]
Yamashita, Yoshiro [1 ]
机构
[1] Tokyo Inst Technol, Interdisciplinary Grad Sch Sci & Engn, Dept Elect Chem, Midori Ku, Yokohama, Kanagawa 2268502, Japan
关键词
CHARGE-TRANSFER COMPLEXES; ELECTRON-DONOR; ACCEPTOR; 11,11,12,12-TETRACYANO-9,10-ANTHRAQUINODIMETHANE; TCAQ; ARRAYS; DIMERS;
D O I
10.1246/cl.2012.482
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
11,11,12,12-Tetracyano-9,10-anthraquinodimethane (TCNAQ) derivatives having four types of aryl substituents, phenyl, biphenyl-4-yl, thien-2-yl, and 2,2'-bithiophen-5-yl groups at their 2-position, were synthesized and characterized. Their crystal structures were determined by single-crystal X-ray structure analysis, revealing that the TCNAQ moiety and electron-donating substituents form donor acceptor-segregated columnar structures. The combination of nonplanar electron acceptor TCNAQ and planar donor units provides a good way to afford segregated columnar structures.
引用
收藏
页码:482 / 484
页数:3
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