Photostabilization of polymeric materials by photoset acrylate coatings

被引:30
作者
Decker, C [1 ]
Zahouily, K [1 ]
机构
[1] Univ Haute Alsace, Dept Photochim Gen, CNRS, UMR 7525,Ecole Natl Super Chim Mulhouse, F-68200 Mulhouse, France
关键词
UV-curing; photostabilization; acrylate coatings;
D O I
10.1016/S0969-806X(01)00474-1
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Different types of polymeric materials have been trade more resistant to photodegradation by protecting their surface with a UV-cured coating containing a HALS radical scavenger and a phenyltriazine UV absorber. The tridimensional polymer network formed by photo polymerization of an aliphatic poly urethane-acrylate telechelic oligomer proved to be very resistant to accelerated weathering in the presence of these light stabilizers. The chemical modifications occurring upon QUV-ageing were monitored by infrared spectroscopy, a very sensitive technique well suited for quantitative analysis at an early, stage of the photodegradation. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:3 / 8
页数:6
相关论文
共 13 条
[1]   Photoinitiated crosslinking polymerisation [J].
Decker, C .
PROGRESS IN POLYMER SCIENCE, 1996, 21 (04) :593-650
[2]   Photodegradation and photooxidation of thermoset and UV-cured acrylate polymers [J].
Decker, C ;
Zahouily, K .
POLYMER DEGRADATION AND STABILITY, 1999, 64 (02) :293-304
[3]   RECOVERY OF PHOTODEGRADED POLYMERS BY SURFACE-TREATMENT [J].
DECKER, C .
MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1992, 57 :103-114
[4]   PHOTODEGRADATION OF UV-CURED COATINGS .2. POLYURETHANE ACRYLATE NETWORKS [J].
DECKER, C ;
MOUSSA, K ;
BENDAIKHA, T .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1991, 29 (05) :739-747
[5]  
Decker C, 1998, J POLYM SCI POL CHEM, V36, P2571, DOI 10.1002/(SICI)1099-0518(199810)36:14<2571::AID-POLA16>3.0.CO
[6]  
2-F
[7]   Light stabilisation of polymers by radiation-cured acrylic coatings [J].
Decker, C ;
Biry, S .
PROGRESS IN ORGANIC COATINGS, 1996, 29 (1-4) :81-87
[8]   PHOTOSTABILIZATION OF ORGANIC COATINGS [J].
DECKER, C ;
BIRY, S ;
ZAHOUILY, K .
POLYMER DEGRADATION AND STABILITY, 1995, 49 (01) :111-119
[9]  
Decker C., 1984, Degradation and Stabilisation of PVC, P81, DOI DOI 10.1007/978-94-009-5618-6_3
[10]  
DECKER C, 1999, P RAD TECH C BERL, P209