Flexible Carbon Nanotube-Graphene/Sulfur Composite Film: Free-Standing Cathode for High-Performance Lithium/Sulfur Batteries

Flexible lithium batteries with high,energy density have recently received tremendous interest due to their potential applications in flexible electronic devices. Herein, we report a novel method to fabricate highly flexible S), composite film as free-standing cathode for flexible Li/S and robust carbon nanotube-graphene/sulfur (CNT.s-RGO/ batteries with increased capacity and significantly improved rate capability. The free-standing CNTs-RGO/S cathode was able to deliver a peak capacity of 911.5 mAh g(sulfur)(-1) (similar to 483 mAh g(electrode)(-1)) and maintain 771.8 mAh g(sulfur)(-1) after 100 charge-discharge cycles at 0,2, indicating a capacity retention of 84.7%, which were both higher than the cathodes assembled without CNTs. Even after 100 cycles, the cathode showed a high tensile strength of 623 MPa. More importantly, the rate capability was improved by introducing CNTs. The CNTs-RGO/S cathode exhibited impressive capacities of 613.1 rnAh g(sulfur)(-1) at 1C with a capacity recuperability of similar to 94% as the current returned to 0.2C. These results demonstrate that the well nanocomposites are of great potential as the cathode for flexible lithium sulfur (Li/S) batteries. Such improved electrochemical properties could be atttibuted to the unique coaxial architecture of the nanocomposite, in which the evenly dispersed CNTs enable electrodes with improved electrical conductivity and mechanical properties and better ability to avoid the aggregation and ensure the dispersive distribution of the sulfur species during the charge/discharge process.