Bis(acetylido) Complexes of Ruthenium(II) Bearing Monodentate Phosphane Ligands

被引：7
|
作者：
Field, Leslie D. [1 ]
Magill, Alison M. [1 ]
Dalgarno, Scott J. [2 ,3 ]
Jensen, Paul [4 ]
机构：
[1] Univ New S Wales, Sch Chem, Kensington, NSW 2052, Australia
[2] Heriot Watt Univ, Sch Engn & Phys Sci Chem, Edinburgh EH14 4AS, Midlothian, Scotland
[3] Univ Missouri, Dept Chem, Columbia, MO 65211 USA
[4] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2008年 / 27期
基金：
澳大利亚研究理事会;
关键词：
Alkyne ligands; Phosphane ligands; Ruthenium;
D O I：
10.1002/ejic.200800495
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Terminal acetylenes react with cis-RuMe2(PMe3)(4) to form the his(acetylido) complexes cis/traps-Ru(C=CR)(2)(PMe3)(4) in good yield. The structures of traps-2 (R = Ph), cis-3 (R = p-C6H4-OMe), trans-4 (R = p-C6H4-Me), cis-6 (R = Me), trans-7 (R = SiMe3) and cis-8 (R = H) were determined by X-ray crystallography. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
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页码：4248 / 4254
页数：7
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