Bis(acetylido) Complexes of Ruthenium(II) Bearing Monodentate Phosphane Ligands

被引：7

作者：

Field, Leslie D. ^{[1
]}

Magill, Alison M. ^{[1
]}

Dalgarno, Scott J. ^{[2
,3
]}

Jensen, Paul ^{[4
]}

机构：

[1] Univ New S Wales, Sch Chem, Kensington, NSW 2052, Australia

[2] Heriot Watt Univ, Sch Engn & Phys Sci Chem, Edinburgh EH14 4AS, Midlothian, Scotland

[3] Univ Missouri, Dept Chem, Columbia, MO 65211 USA

[4] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2008年 / 27期

基金：

澳大利亚研究理事会;

关键词：

Alkyne ligands; Phosphane ligands; Ruthenium;

D O I：

10.1002/ejic.200800495

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Terminal acetylenes react with cis-RuMe2(PMe3)(4) to form the his(acetylido) complexes cis/traps-Ru(C=CR)(2)(PMe3)(4) in good yield. The structures of traps-2 (R = Ph), cis-3 (R = p-C6H4-OMe), trans-4 (R = p-C6H4-Me), cis-6 (R = Me), trans-7 (R = SiMe3) and cis-8 (R = H) were determined by X-ray crystallography. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

引用

页码：4248 / 4254

页数：7

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