Novel chiral and achiral NCN pincer complexes based on 1,3-Bis(1H-1,2,4-triazol-1-ylmethyl)benzene

被引：43

作者：

Díez-Barra, E ^{[1
]}

Guerra, J ^{[1
]}

López-Solera, I ^{[1
]}

Merino, S ^{[1
]}

Rodríguez-López, J ^{[1
]}

Sánehez-Verdú, P ^{[1
]}

Tejeda, J ^{[1
]}

机构：

[1] Univ Castilla La Mancha, Fac Ciencias Quim, E-13071 Ciudad Real, Spain

来源：

ORGANOMETALLICS | 2003年 / 22卷 / 03期

关键词：

D O I：

10.1021/om020764i

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

NCN pincer ligands based on 1,2,4-triazole and their corresponding palladium(II) complexes have been synthesized by the reaction of 1,3-bis(1H-1,2,4-triazol-1-ylmethyl)benzene derivatives with palladium(II) acetate. All compounds are ortho,ortho-metalated. Chiral complexes were obtained by using pincer ligands with substituents on the arms. The chiral complexes are conformationally rigid up to 150 degreesC.

引用

页码：541 / 547

页数：7

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