Microwave-assisted synthesis of spherical monodispersed magnesium fluoride

被引：26

作者：

Pietrowski, Mariusz ^{[1
]}

Wojciechowska, Maria ^{[1
]}

机构：

[1] Adam Mickiewicz Univ Poznan, Fac Chem, PL-60780 Poznan, Poland

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2007年 / 128卷 / 03期

关键词：

monodispersed magnesium fluoride; spherical magnesium fluoride; microwave-assisted synthesis; MgF2;

D O I：

10.1016/j.jfluchem.2006.12.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Spherical monodispersed magnesium fluoride has been obtained using the microwave-assisted precipitation technique from magnesium nitrate and ammonium fluoride solutions. Studies aimed at optimizing synthesis conditions from the point of view of preparing spherical MgF2 particles of possibly high monodispersity were performed. Spherical MgF2 particles of 0.25-0.36 mu m in diameter have been obtained with relative standard deviation from the average value ranging from 7 to 15%. It has been established that a certain optimal range of Mg(NO3)(2) and NH4F concentrations exists that enables a highly monodispersed MgF2 to be prepared. The range is narrow (0.01-0.03 mol dm(-3)) for both precursors. Spherical MgF2 particles have been characterized by SEM, XRD, DTG/DTA and FTIR techniques. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：219 / 223

页数：5

共 36 条

[1] HIGH-PURITY, MONODISPERSE TIO2 POWDERS BY HYDROLYSIS OF TITANIUM TETRAETHOXIDE .1. SYNTHESIS AND PHYSICAL-PROPERTIES
BARRINGER, EA
BOWEN, HK
[J]. LANGMUIR, 1985, 1 (04) : 414 - 420
[2] Comparison of different high and low index materials in the manufacture of high laser damage threshold mirrors at the 351 nm wavelength
Bazin, N
Andrew, JE
Mcinnes, HA
[J]. JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 1998, 13 (1-3) : 757 - 761
[3] FARADAY M, 1857, PHILOS T ROY SOC LON, V147, P145, DOI [10.1098/rstl.1857.0011, DOI 10.1098/RSTL.1857.0011]
[4] Preparation and characterization of MgF2 thin film by a trifluoroacetic acid method
Fujihara, S
Tada, M
Kimura, T
[J]. THIN SOLID FILMS, 1997, 304 (1-2) : 252 - 255
[5] Using sonochemistry for the fabrication of nanomaterials
Gedanken, A
[J]. ULTRASONICS SONOCHEMISTRY, 2004, 11 (02) : 47 - 55
[6] The formation of uniform colloidal particles of magnesium fluoride and sodium magnesium fluoride
Hsu, WP
Zhong, QP
Matijevic, E
[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1996, 181 (01) : 142 - 148
[7] Solvothermal synthesis of hollow ZnS spheres
Hu, ZS
Li, LY
Zhou, XD
Fu, X
Gu, GH
[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2006, 294 (02) : 328 - 333
[8] Synthesis of morphologically controlled lanthanum carbonate particles using ultrasound irradiation
Jeevanandam, P
Koltypin, Y
Palchik, O
Gedanken, A
[J]. JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (03) : 869 - 873
[9] Synthesis of narrow size distribution sub-micron TiO2 spheres
Keshmiri, M
Troczynski, T
[J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 2002, 311 (01) : 89 - 92
[10] Synthesis of lanthanide fluoride nanoparticles of varying shape and size
Lemyre, JL
Ritcey, AM
[J]. CHEMISTRY OF MATERIALS, 2005, 17 (11) : 3040 - 3043

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