[(Z)-O-Ethyl-N-(p-tolyl)thiocarbamato-κS](triphenylphosphine)-κP]gold(I)

被引:3
|
作者
Tadbuppa, Primjira P. [2 ]
Tiekink, Edward R. T. [1 ]
机构
[1] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
[2] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词
CARBONIMIDOTHIOATES; PH;
D O I
10.1107/S1600536809047618
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, [Au(C(10)H(12)NOS)(C(18)H(15)P)], features a linear S, P-donor set about the central Au atom. The thiocarbamate ligand is orientated to place the aryl ring in close proximity to Au [the closest Au center dot center dot center dot C distance is 3.238 (4) angstrom], which results in a small deviation from the ideal linear P-Au-S geometry.
引用
收藏
页码:M1587 / U822
页数:10
相关论文
共 32 条
  • [21] [(Z)-O-Ethyl N-phenylthiocarbamato-κS](tricyclohexylphosphine-κP)gold(I): a monoclinic polymorph
    Tadbuppa, Primjira P.
    Tiekink, Edward R. T.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M402 - U624
  • [22] [(Z)-N,O-Disopropylthiocarbamato-κS](tricyclohexylphosphine-κP)gold(I)
    Tadbuppa, Primjira P.
    Tiekink, Edward R. T.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M1570 - U656
  • [23] [(Z)-N-Isopropyl-O-methylthiocarbamato-κS](tri-p-tolylphosphine-κP)gold(I)
    Tadbuppa, Primjira P.
    Tiekink, Edward R. T.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M1557 - U544
  • [24] [(Z)-O-Isopropyl N-phenylthiocarbamato-κS](tricyclohexylphosphine- κP)gold(I)
    Tadbuppa, Primjira P.
    Tiekink, Edward R. T.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M429 - U868
  • [25] Crystal structure of [O-ethyl N-(4-nitrophenyl)thiocarbamato-κS] (tri-4-tolylphosphine-κP)gold(1) tetrahydrofuran solvate, C30H30AuN2O3PS, C4H8O
    Kuan, Fong Sheen
    Tiekink, Edward R. T.
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2020, 235 (05): : 1267 - 1269
  • [26] [μ-1,1′-Bis(diphenylphosphino)ferrocene]bis{[(Z)-O-ethyl N-phenylthiocarbamato-κS]gold(I)} dichloromethane solvate
    Ho, Soo Yei
    Tiekink, Edward R. T.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M608 - U181
  • [27] [(Z)-Isopropoxy(4-nitrophenylimino)methanethiolato-κS](tricyclohexylphosphine-κP)gold(I)
    Ho, Soo Yei
    Tiekink, Edward R. T.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M1415 - U1581
  • [28] [(Z)-N-(3-Fluorophenyl)-O-methylthiocarbamato-κS](triphenylphosphane-κP)gold(I): crystal structure, Hirshfeld surface analysis and computational study
    Yeo, Chien Ing
    Tan, Sang Loon
    Kwong, Huey Chong
    Tiekink, Edward R. T.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2020, 76 : 1284 - +
  • [29] Crystal structure of (μ2-1,1′-bis(diphenylphosphino)butane-κ2P,P′)-bis [(Z)-N-(3-fluorophenyl)-O-methylthiocarbamato-κS]-di-gold(I), C44H42Au2F2N2O2P2S2
    Yeo, Chien Ing
    Tiekink, Edward R. T.
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2020, 235 (06): : 1445 - 1448
  • [30] Pathogenic Gram-positive bacteria are highly sensitive to triphenylphosphanegold(O-alkylthiocarbamates), Ph3PAu[SC(OR)=N(p-tolyl)] (R=Me, Et and iPr)
    Yeo, Chien Ing
    Sim, Jiun-Horng
    Khoo, Chai-Hoon
    Goh, Zheng-Jie
    Ang, Kok-Pian
    Cheah, Yoke-Kqueen
    Fairuz, Zainal Abidin
    Halim, Siti Nadiah Binti Abdul
    Ng, Seik Weng
    Seng, Hoi-Ling
    Tiekink, Edward R. T.
    GOLD BULLETIN, 2013, 46 (03): : 145 - 152