Mesoporous aluminosilicate nanocage-catalyzed three-component coupling reaction: an expedient synthesis of α-aminophosphonates

被引：46

作者：

Vinu, Ajayan ^{[2
]}

Kalita, Pranjal ^{[2
]}

Balasubramanian, Veerappan V. ^{[2
]}

Oveisi, Hamid ^{[2
]}

Selvan, Tamil ^{[2
]}

Mano, Ajayan ^{[2
]}

Chari, Murugulla A. ^{[2
]}

Reddy, B. V. Subba ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Discovery Lab, Hyderabad 500007, Andhra Pradesh, India

[2] Natl Inst Mat Sci, Int Ctr Mat Nanoarchitecton, WPI Res Ctr, Tsukuba, Ibaraki 3050044, Japan

来源：

TETRAHEDRON LETTERS | 2009年 / 50卷 / 51期

关键词：

Catalysis; Synthesis; Mesoporous; Heterogeneous; Aminophosphonates; ONE-POT SYNTHESIS; ANTIBACTERIAL AGENTS; AMINO-PHOSPHONATES; EFFICIENT SYNTHESIS; MOLECULAR-SIEVES; PHOSPHONOPEPTIDES; ACID;

D O I：

10.1016/j.tetlet.2009.10.003

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Here we demonstrate for the first time the synthesis of alpha-aminophosphonates through the three-component coupling reaction of aldehydes, amines, and diethyl phosphite by using highly acidic 3D mesoporous aluminosilicate nanocage catalyst, which gave excellent yield with a high selectivity in a short reaction time due to its high acidity, 3D pores, and a huge space in the nanocages. (c) 2009 Elsevier Ltd. All rights reserved.

引用

页码：7132 / 7136

页数：5