Recent developments in catalysis with Pickering Emulsions

被引:95
作者
Chang, Fuqiang [1 ]
Vis, Carolien M. [2 ]
Ciptonugroho, Wirawan [2 ]
Bruijnincx, Pieter C. A. [1 ]
机构
[1] Univ Utrecht, Debye Inst Nanomat Sci, Organ Chem & Catalysis, Univ Weg 99, NL-3584 CG Utrecht, Netherlands
[2] Univ Utrecht, Inorgan Chem & Catalysis, Debye Inst Nanomat Sci, Univ Weg 99, NL-3584 CG Utrecht, Netherlands
基金
荷兰研究理事会;
关键词
IN-WATER EMULSIONS; LIQUID-LIQUID INTERFACE; SILICA NANOPARTICLES; JANUS PARTICLES; SELECTIVE OXIDATION; PHASE INVERSION; SURFACE; DROPLETS; COMPARTMENTALIZATION; STABILIZATION;
D O I
10.1039/d0gc03604h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Pickering emulsions (PEs), emulsions stabilized by solid emulsifiers, are already of great importance for the food, pharmaceutical and biomedical industry. More recently, PEs are also being increasingly used as advanced catalytic systems for green chemical transformations. These efforts aim to combine the green credentials of biphasic catalysis with the intrinsic advantages offered by PEs, which include increased stability and interfacial area. Here, we provide a review of the recent advances in the field of PE catalysis, emphasizing the developments in the design of (functional) solid stabilizing particles, the range of accessible catalytic reactions and reaction conditions, as well as advances in reactor engineering, such as the application of PE catalysis in continuous flow systems.
引用
收藏
页码:2575 / 2594
页数:20
相关论文
共 134 条
[1]   The United Nations sustainability goals: How can sustainable chemistry contribute? [J].
Anastas, Paul T. ;
Zimmerman, Julie B. .
CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY, 2018, 13 :150-153
[2]   Stimuli-Responsive Bicomponent Polymer Janus Particles by "Grafting from"/"Grafting to" Approaches [J].
Berger, Sebastian ;
Synytska, Alla ;
Ionov, Leonid ;
Eichhorn, Klaus-Jochen ;
Stamm, Manfred .
MACROMOLECULES, 2008, 41 (24) :9669-9676
[3]   Synergistic interaction in emulsions stabilized by a mixture of silica nanoparticles and cationic surfactant [J].
Binks, Bernard P. ;
Rodrigues, Jhonny A. ;
Frith, William J. .
LANGMUIR, 2007, 23 (07) :3626-3636
[4]   Temperature-induced inversion of nanoparticle-stabilized emulsions [J].
Binks, BP ;
Murakami, R ;
Armes, SP ;
Fujii, S .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (30) :4795-4798
[5]   Nanoparticle silica-stabilised oil-in-water emulsions: improving emulsion stability [J].
Binks, BP ;
Whitby, CP .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2005, 253 (1-3) :105-115
[6]   Catastrophic phase inversion of water-in-oil emulsions stabilized by hydrophobic silica [J].
Binks, BP ;
Lumsdon, SO .
LANGMUIR, 2000, 16 (06) :2539-2547
[7]   Particles adsorbed at the oil-water interface: A theoretical comparison between spheres of uniform wettability and "Janus" particles [J].
Binks, BP ;
Fletcher, PDI .
LANGMUIR, 2001, 17 (16) :4708-4710
[8]   Clickable Janus Particles [J].
Bradley, Laura C. ;
Stebe, Kathleen J. ;
Lee, Daeyeon .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (36) :11437-11440
[9]   2,2,5,5-Tetramethyltetrahydrofuran (TMTHF): a non-polar, non-peroxide forming ether replacement for hazardous hydrocarbon solvents [J].
Byrne, Fergal ;
Forier, Bart ;
Bossaert, Greet ;
Hoebers, Charly ;
Farmer, Thomas J. ;
Clark, James H. ;
Hunt, Andrew J. .
GREEN CHEMISTRY, 2017, 19 (15) :3671-3678
[10]   Self-Assembly of Amphiphilic Janus Particles into Monolayer Capsules for Enhanced Enzyme Catalysis in Organic Media [J].
Cao, Wei ;
Huang, Renliang ;
Qi, Wei ;
Su, Rongxin ;
He, Zhimin .
ACS APPLIED MATERIALS & INTERFACES, 2015, 7 (01) :465-473