Catalytic oxidation of aliphatic alcohols in the tetraaquapalladium(II) complex-iron(III)-dioxygen system

被引：4
|
作者：
Potekhin, VV [1 ]
Solov'eva, SN [1 ]
Potekhin, VM [1 ]
机构：
[1] Tech Univ, St Petersburg State Technol Inst, St Petersburg 198013, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2003年 / 52卷 / 12期
关键词：
oxidation of alcohols; tetraaquapalladium(II) complex; iron(III); oxygen;
D O I：
10.1023/B:RUCB.0000019884.21081.a0
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The selective low-temperature (40-70degreesC) catalytic oxidation of methanol, propan-1-ol, and propan-2-ol in the presence of the tetraaquapalladium(II) complex and iron(ill) ions and/or molecular oxygen as cooxidants was studied. The corresponding carbonyl compound is the product of alcohol oxidation. The kinetic regularities of the reaction were established. In the reaction mechanism proposed, the key step is palladium(I) formation.
引用
收藏
页码：2668 / 2674
页数：7
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