VANARSITE, PACKRATITE, MORRISONITE, AND GATEWAYITE: FOUR NEW MINERALS CONTAINING THE [As3+V4+,5+12As5+6O51] HETEROPOLYANION, A NOVEL POLYOKOMETALATE CLUSTER

被引：17
|
作者：
Kampf, Anthony R. [1 ]
Hughes, John M. [2 ]
Nash, Barbara P. [3 ]
Marty, Joe [4 ]
机构：
[1] Nat Hist Museum Los Angeles County, Dept Mineral Sci, 900 Exposit Boulevard, Los Angeles, CA 90007 USA
[2] Univ Vermont, Dept Geol, 180 Colchester Ave, Burlington, VT 05405 USA
[3] Univ Utah, Dept Geol & Geophys, Salt Lake City, UT 84112 USA
[4] 5199 E Silver Oak Rd, Salt Lake City, UT 84108 USA
来源：
CANADIAN MINERALOGIST | 2016年 / 54卷 / 01期
基金：
美国国家科学基金会;
关键词：
Vanarsite; packratite; morrisonite; gatewayite; new mineral; crystal structure; polyoxometalate; Packrat mine; Gateway; Colorado; CRYSTAL-STRUCTURE; VALENCE; CHEMISTRY;
D O I：
10.3749/canmin.1500062
中图分类号：
P57 [矿物学];
学科分类号：
070901 ;
摘要：
Vanarsite (IMA2014-031), NaCa12(As3+V3.54+V8.55+As65+O51)(2).78H2O, packratite (IMA2014-059), Ca-11(As3+V24+V105+As65+O51)(2).83H(2)O, morrisonite (IMA2014-088), Ca-11(As3+V24+V105+As65+O51)(2).78H2O, and gatewayite (IMA2014-096), Ca-6(As3+V34+V95+As65+O51).31H(2)O, are four new minerals from the Packrat mine, Gateway district, Mesa County, Colorado, U.S.A. Crystals of all four new minerals are very dark blue to greenish-blue blades. They are found together on montroseite- and corvusite-bearing sandstone in association with pharmacolite. Vanarsite is monoclinic, P2(1)/c, a 25.8902(8), b 10.9468(3), c 28.2980(8) A, beta 102.252(1), V 7828.9(3) A(3), and Z = 2. Packratite is triclinic, P (1) over bar, a 18.0572(4), b 19.4126(4), c 24.0586(17) A, alpha 87.364(6), beta 86.266(6), gamma 79.267(6), V 8263.4(7) A(3), and Z = 2. Morrisonite is monoclinic, P2(1)/c, a 14.9566(18), b 48.208(6), c 23.836(3) A, beta 90.034(6), V 17187(4) A(3), and Z = 4. Gatewayite is monoclinic, P2(1), a 11.1850(4), b 16.8528(4), c 20.7146(15) A, beta 91.166(6), V 3903.9(3) A(3), and Z = 2. The structures of all four new minerals contain the novel polyoxometalate-like heteropolyanion, [As3+As65+V2+x4+V10x5+O51]((11+x)) (x = 0 to 1.5), which is new to science.
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页码：145 / 162
页数：18
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