A novel spiro-functionalized polyfluorene derivative with solubilizing side chains

被引:60
作者
Vak, D [1 ]
Chun, C [1 ]
Lee, CL [1 ]
Kim, JJ [1 ]
Kim, DY [1 ]
机构
[1] Kwangju Inst Sci & Technol, Ctr Frontier Mat, Dept Mat Sci & Engn, Gwangju, South Korea
关键词
D O I
10.1039/b317028d
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report on a new polyfluorene derivative containing a spiroanthracenefluorene unit with a remote C-10 position that provides facile substitution of alkyl groups. An ethylhexyl group was introduced into the spiroanthracenefluorene unit and the ethylhexyl-substituted spiroanthracenefluorene was polymerized via an Ni(0)- mediated polymerization. The polymer showed a high spectral stability with respect to heat treatment, UV irradiation, and high current passage. A light-emitting device based on this polymer showed an emission in a deep blue region with CIE color coordinates of x = 0.17 and y = 0.12.
引用
收藏
页码:1342 / 1346
页数:5
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