Overview of Photocatalytic Membrane Reactors in Organic Synthesis, Energy Storage and Environmental Applications

被引:46
作者
Molinari, Raffaele [1 ]
Lavorato, Cristina [1 ]
Argurio, Pietro [1 ]
Szymanski, Kacper [2 ]
Darowna, Dominika [2 ]
Mozia, Sylwia [2 ]
机构
[1] Univ Calabria, Dept Environm & Chem Engn, Via P Bucci 44-A, I-87036 Arcavacata Di Rende, Italy
[2] West Pomeranian Univ Technol, Inst Chem Technol & Environm Engn, Fac Chem Technol & Engn, Ul Pulaskiego 10, PL-70322 Szczecin, Poland
来源
CATALYSTS | 2019年 / 9卷 / 03期
关键词
photocatalytic membrane reactor; photocatalysis; photocatalyst; membrane separation; photocatalytic membrane; organic synthesis; water treatment; wastewater treatment; ADVANCED OXIDATION PROCESSES; HOLLOW-FIBER MEMBRANE; OF-THE-ART; WASTE-WATER; CARBON-DIOXIDE; SECONDARY EFFLUENT; CO2; REDUCTION; HETEROGENEOUS PHOTOCATALYSIS; COMPOSITE MEMBRANES; HYDROGEN-PRODUCTION;
D O I
10.3390/catal9030239
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This paper presents an overview of recent reports on photocatalytic membrane reactors (PMRs) in organic synthesis as well as water and wastewater treatment. A brief introduction to slurry PMRs and the systems equipped with photocatalytic membranes (PMs) is given. The methods of PM production are also presented. Moreover, the process parameters affecting the performance of PMRs are characterized. The applications of PMRs in organic synthesis are discussed, including photocatalytic conversion of CO2, synthesis of KA oil by photocatalytic oxidation, conversion of acetophenone to phenylethanol, synthesis of vanillin and phenol, as well as hydrogen production. Furthermore, the configurations and applications of PMRs for removal of organic contaminants from model solutions, natural water and municipal or industrial wastewater are described. It was concluded that PMRs represent a promising green technology; however, before the application in industry, additional studies are still required. These should be aimed at improvement of process efficiency, mainly by development and application of visible light active photocatalysts and novel membranes resistant to the harsh conditions prevailing in these systems.
引用
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页数:38
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