Synthesis and spectroscopic studies of mixed-ligand complexes of lead(II) hexafluoroacetylacetonate including the crystal structure of [Pb2(phen)4(hfa)2(-NO3)2]

被引：14

作者：

Marandi, Farzin ^{[1
]}

Chantrapromma, Suchada ^{[2
]}

Fun, Hoong-Kun ^{[3
]}

机构：

[1] Payame Noor Univ, Dept Sci, Zanjan, Iran

[2] Prince Songkla Univ, Dept Chem, Fac Sci, Hat Yai 90112, Songkhla, Thailand

[3] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, Usm Penang 11800, Malaysia

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2009年 / 62卷 / 02期

关键词：

Spectroscopic studies; Crystal structure; Lead(II) complex; Intermolecular interactions; INTERMOLECULAR INTERACTIONS; CADMIUM(II) COMPLEXES; PI INTERACTIONS; FLUORINE; ANION; 2,2'-BIPYRIDINE; ARCHITECTURES; POLYMER; AZIDO;

D O I：

10.1080/00958970802203774

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Four new mixed-ligand complexes of lead(II) hexafluoroacetylacetonate (hfa) were synthesized and characterized by elemental analyses, IR, 1H and 13C NMR spectroscopy. The single-crystal structure of [Pb2(phen)4(hfa)2(-NO3)2] (1) shows the complex to be a dimeric unit as a result of nitrate bridging. The coordination number of Pb(II) is eight with four N-donors from a phen and four O-donors from the hexafluoroacetylacetonate and nitrate ligands. This dimeric complex is the first fluorine -diketonate and nitrate mixed-ligand lead(II) complex that has been characterized by X-ray structural analysis. The supramolecular features in this complex are controlled by weak directional intermolecular interactions and aromatic - stacking interactions.

引用

页码：249 / 256

页数：8

共 50 条

[21] Synthesis and crystal structure of [La(phen)2(H2O)2(NO3)2]NO3•2(phen)(H2O) with phen=1,10-phenanthroline
Zheng, YQ
Zhou, LX
Lin, JL
Zhang, SW
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2000, 626 (08): : 1715 - 1717
[22] CRYSTAL STRUCTURES OF MIXED-LIGAND BINUCLEAR Zn(II) 2-IODOBENZOATE COMPLEXES WITH 4-ETHYL- AND 3-CHLOROPYRIDINE
Bondarenko, M. A.
Adonin, S.
JOURNAL OF STRUCTURAL CHEMISTRY, 2021, 62 (08) : 1251 - 1256
[23] Complexation of lead(II) by nicotinamide (nia):: Crystal structure of polymeric Pb(nia)(NO3)2
Najafpour, Mohammad Mahdi
Lis, Tadeusz
Holynska, Malgorzata
INORGANICA CHIMICA ACTA, 2007, 360 (10) : 3452 - 3455
[24] PALLADIUM(II) MIXED-LIGAND COMPLEXES CONTAINING 2,2′- BIPYRIDINE DERIVATIVES AND 4-TOLUENESULFONYL-L-SERINE: SYNTHESIS, CHARACTERIZATION, AND CRYSTAL STRUCTURE DETERMINATION
Mehdipour, Ebrahim
Bahrami, Homayoon
Shamaei, Shabnam
Amani, Vahid
Notash, Behrouz
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2015, 190 (10) : 1588 - 1598
[25] Syntheses and characterization of mixed-anions lead(II) complexes, [Pb(phen)2(CH3COO)]X (X=NCS-, NO3- and ClO4-), crystal structure of [Pb(phen)2(CH3COO)][(ClO4)
Morsali, A
Mahjoub, AR
Darzi, SJ
Soltanian, MJ
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2003, 629 (14): : 2596 - 2599
[26] Synthesis, Crystal Structure and Property of Cu Pb2(OH)2Cl3
黄荣荣
张素允
崔美艳
徐军
何长振
结构化学, 2015, 34 (04) : 594 - 598
[27] Synthesis and crystal structure of quaternary mixed anion complex of lanthanide [Pr(CH3CH2COO)2(NO3)(phen)2]
Zhu, LG
Yu, QS
Xiu, XP
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 1999, 15 (03) : 319 - 323
[28] Synthesis and characterization of mixed-ligand Zn(II) and Cu(II) complexes including polyamines and dicyano-dithiolate(2-): In vitro cytotoxic activity of Cu(II) compounds
Adhikari, Suman
Bhattacharjee, Tirtha
Butcher, Raymond J.
Porchia, Marina
De Franco, Michele
Marzano, Cristina
Gandin, Valentina
Tisato, Francesco
INORGANICA CHIMICA ACTA, 2019, 498
[29] Synthesis, characterization, and luminescence of zinc(II) and cadmium(II) coordination complexes: [Zn(phen)2(CH3COO)](ClO4), [Zn(bpy)2(ClO4)](ClO4), and [Cd(phen)2(NO3)2]
Kani, Ibrahim
Kurtca, Mehmet
TURKISH JOURNAL OF CHEMISTRY, 2013, 37 (06) : 993 - 1006
[30] Lead(II) complexes of 2,2′-diamino-4,4′-bithiazole (DABTZ) including crystal structure of a novel 1D chain polymer, [PB(DABTZ)(μ-SCN)(μ-NO3)]n
Abedini, J
Morsali, A
Kempe, R
Hertle, I
JOURNAL OF COORDINATION CHEMISTRY, 2005, 58 (18) : 1719 - 1726

← 1 2 3 4 5 →