Light-responsive self-assembly of a cationic azobenzene surfactant at high concentration

被引:8
|
作者
Blayo, Camille [1 ]
Kelly, Elaine A. [2 ]
Houston, Judith E. [3 ]
Khunti, Nikul [4 ]
Cowieson, Nathan P. [4 ]
Evans, Rachel C. [2 ]
机构
[1] Trinity Coll Dublin, Coll Green, Sch Chem, Dublin 2, Ireland
[2] Dept Mat Sci & Met, 27 Charles Babbage Rd, Cambridge CB3 0FS, England
[3] European Spallat Source ESS, Odarslovsvagen 113, S-22592 Lund, Sweden
[4] Diamond Light Source, Harwell Sci & Innovat Campus, Didcot OX11 0DE, Oxon, England
基金
英国工程与自然科学研究理事会;
关键词
CRYSTALLINE; WATER; ISOMERIZATION; SERIES; CIS;
D O I
10.1039/d0sm01512a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The formation of high-concentration mesophases by a cationic azobenzene photosurfactant is described for the first time. Using a combination of polarised optical microscopy and small-angle X-ray scattering, optically anisotropic, self-assembled structures with long-range order are reported. The mesophases are disrupted or lost upon UV irradiation.
引用
收藏
页码:9183 / 9187
页数:5
相关论文
共 50 条
  • [41] Preparation and photochromic properties of layer-by-layer self-assembly films and light-responsive micelles based on amphiphilic naphthopyran derivative
    Zhang, Meiduo
    Li, Dehua
    He, Yi
    Wang, Guang
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2015, 151 : 525 - 531
  • [42] Self-Assembly of a Fluorocarbon-Hydrocarbon Hybrid Surfactant: Dependence of Morphology on Surfactant Concentration and Time
    Takahashi, Yutaka
    Kondo, Yukishige
    Schmidt, Judith
    Talmon, Yeshayahu
    JOURNAL OF PHYSICAL CHEMISTRY B, 2010, 114 (42): : 13319 - 13325
  • [43] Photo-responsive supramolecular self-assembly and disassembly of an azobenzene-containing block copolymer
    Jin, Qiao
    Liu, Gongyan
    Liu, Xiangsheng
    Ji, Jian
    SOFT MATTER, 2010, 6 (21) : 5589 - 5595
  • [44] Size and shape matter for micellar catalysis using light-responsive azobenzene surfactants
    Blayo, Camille
    Jones, Beatrice E.
    Bennison, Michael J.
    Evans, Rachel C.
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2024, : 138 - 144
  • [45] Light-responsive surfactants: Photochromic properties of water-soluble azobenzene derivatives
    Orlikowska, Hanna
    Sobolewska, Anna
    Bartkiewicz, Stanislaw
    JOURNAL OF MOLECULAR LIQUIDS, 2020, 316
  • [46] Thermo- and Light-Responsive Polymers Containing Photoswitchable Azobenzene End Groups
    Jochum, Florian D.
    zur Borg, Lisa
    Roth, Peter J.
    Theato, Patrick
    MACROMOLECULES, 2009, 42 (20) : 7854 - 7862
  • [47] Self-Assembly of the Cationic Gemini Surfactant in Water: From Elastic Gels to Viscoelastic Solutions
    Li, Qintang
    Zhao, Chunhua
    Zhu, Chengya
    Wang, Ruirui
    Zhou, Yaochun
    Lin, Mingyu
    Zhuang, Wenchang
    NANO, 2023,
  • [48] A Supramolecular Amphiphile Based on Calix[4]resorcinarene and Cationic Surfactant for Controlled Self-Assembly
    Kharlamov, Sergey V.
    Kashapov, Ruslan R.
    Pashirova, Tatiana N.
    Zhiltsova, Elena P.
    Lukashenko, Svetlana S.
    Ziganshina, Albina Yu.
    Gubaidullin, Aidar T.
    Zakharova, Lucia Ya.
    Gruner, Margit
    Habicher, Wolf D.
    Konovalov, Alexander I.
    JOURNAL OF PHYSICAL CHEMISTRY C, 2013, 117 (39): : 20280 - 20288
  • [49] Highly-ordered selective self-assembly of a trimeric cationic surfactant on a mica surface
    Hou, Yanbo
    Cao, Meiwen
    Deng, Manli
    Wang, Yilin
    LANGMUIR, 2008, 24 (19) : 10572 - 10574
  • [50] Self-assembly of cationic pyrene nanotubes
    Chen, Yulan
    Zhu, Bo
    Han, Yang
    Bo, Zhishan
    JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (11) : 4927 - 4931