Intermolecular recognition and crystal packing in molybdenum and tungsten coordination polymers as deduced from powder X-ray diffraction data

被引：15

作者：

Chisholm, MH ^{[1
]}

Wilson, PJ ^{[1
]}

Woodward, PM ^{[1
]}

机构：

[1] Ohio State Univ, Dept Chem, Newman & Wolfrom Lab, Columbus, OH 43210 USA

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 06期

关键词：

D O I：

10.1039/b200362g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The molecular conformations and packing of [((BuCO2)-Bu-t) M-3(2)(mu-X) M-2((O2CBu)-Bu-t)(3)], where M = Mo and W, and X = oxalate and perfluoroterephthalate, determined in the solid-state from powder X-ray diffraction analysis, reveal one-dimensional coordination polymers involving pivalate-oxygen to metal interactions (X = perfluoroterephthalate), and oxalate- as well as pivalate-oxygen to metal bonds (X = oxalate), and allows explanation of the unusual state-dependent chromic properties of these compounds.

引用

页码：566 / 567

页数：2

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