Oxidative Fusion Reactions of meso-(Diarylamino)porphyrins

被引：87

作者：

Fukui, Norihito ^{[1
]}

Cha, Won-Young ^{[2
]}

Lee, Sangsu ^{[2
]}

Tokuji, Sumito ^{[1
]}

Kim, Dongho ^{[2
]}

Yorimitsu, Hideki ^{[1
]}

Osuka, Atsuhiro ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Sakyo Ku, Kyoto 6068502, Japan

[2] Yonsei Univ, Dept Chem & Spect Funct Elect Syst, Seoul 120749, South Korea

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 37期

基金：

新加坡国家研究基金会;

关键词：

aminoporphyrins; conjugation; fluorescence; fusion reactions; porphyrinoids; SENSITIZED SOLAR-CELLS; NEAR-IR ABSORPTION; 2-PHOTON ABSORPTION; EFFICIENT SYNTHESIS; PORPHYRIN; COMPLEXES; FACILE; CYCLIZATION; ZINC; NHC;

D O I：

10.1002/anie.201304794

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Creating cool fusion: The oxidative fusion of meso-(diarylamino)porphyrins depends heavily on the structures of the diarylamino groups. Bridged diarylamino groups result in the oxidative fusion of 3,5-di-tert-butylphenyl groups to the porphyrin moiety (blue), while non-bridged diarylamino groups invoke formation of nitrogen-embedded aminophenylene-fused porphyrins (red). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：9728 / 9732

页数：5

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