We have investigated the effect of Fe doping on the structural and electrical properties of the double perovskite oxide Sr2Mg1-xFe5MoO6-delta (x = 0, 0.2, 0.5). The structure of the Fe doped compounds is tetragonal, unlike the triclinic undoped compound. The Fe doping favors the reduction of Mo6+ to Mo5+, which plays a vital role in determining the electrical properties. The conductivity increases with increasing Fe content. The samples were found to be stable in both oxidizing and reducing conditions. (C) 2013 Elsevier B.V. All rights reserved.
机构:
Natl Inst Mat Sci NIMS, Int Ctr Mat Nanoarchitecton WPI MANA, Namiki 1-1, Tsukuba, Ibaraki 3050044, JapanNatl Inst Mat Sci NIMS, Int Ctr Mat Nanoarchitecton WPI MANA, Namiki 1-1, Tsukuba, Ibaraki 3050044, Japan
机构:
State Key Laboratory of New Ceramics and Fine Processing, Beijing Key Lab of Fine Ceramics, Institute of Nuclear and New Energy Technology, Tsinghua UniversityState Key Laboratory of New Ceramics and Fine Processing, Beijing Key Lab of Fine Ceramics, Institute of Nuclear and New Energy Technology, Tsinghua University
艾德生
马景陶
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机构:
State Key Laboratory of New Ceramics and Fine Processing, Beijing Key Lab of Fine Ceramics, Institute of Nuclear and New Energy Technology, Tsinghua UniversityState Key Laboratory of New Ceramics and Fine Processing, Beijing Key Lab of Fine Ceramics, Institute of Nuclear and New Energy Technology, Tsinghua University
马景陶
邓长生
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机构:
State Key Laboratory of New Ceramics and Fine Processing, Beijing Key Lab of Fine Ceramics, Institute of Nuclear and New Energy Technology, Tsinghua UniversityState Key Laboratory of New Ceramics and Fine Processing, Beijing Key Lab of Fine Ceramics, Institute of Nuclear and New Energy Technology, Tsinghua University
机构:
Natl Inst Mat Sci NIMS, Int Ctr Mat Nanoarchitecton WPI MANA, Namiki 1-1, Tsukuba, Ibaraki 3050044, JapanNatl Inst Mat Sci NIMS, Int Ctr Mat Nanoarchitecton WPI MANA, Namiki 1-1, Tsukuba, Ibaraki 3050044, Japan
机构:
State Key Laboratory of New Ceramics and Fine Processing, Beijing Key Lab of Fine Ceramics, Institute of Nuclear and New Energy Technology, Tsinghua UniversityState Key Laboratory of New Ceramics and Fine Processing, Beijing Key Lab of Fine Ceramics, Institute of Nuclear and New Energy Technology, Tsinghua University
艾德生
马景陶
论文数: 0引用数: 0
h-index: 0
机构:
State Key Laboratory of New Ceramics and Fine Processing, Beijing Key Lab of Fine Ceramics, Institute of Nuclear and New Energy Technology, Tsinghua UniversityState Key Laboratory of New Ceramics and Fine Processing, Beijing Key Lab of Fine Ceramics, Institute of Nuclear and New Energy Technology, Tsinghua University
马景陶
邓长生
论文数: 0引用数: 0
h-index: 0
机构:
State Key Laboratory of New Ceramics and Fine Processing, Beijing Key Lab of Fine Ceramics, Institute of Nuclear and New Energy Technology, Tsinghua UniversityState Key Laboratory of New Ceramics and Fine Processing, Beijing Key Lab of Fine Ceramics, Institute of Nuclear and New Energy Technology, Tsinghua University