Syntheses and characterizations of two-dimensional lanthanide coordination polymers based on anthraquinone-1,4,5,8-tetracarboxylic acid

被引：11
|
作者：
Yan, Wei-Hong [1 ,2 ]
Bao, Song-Song [1 ]
Ding, Liu-liu [1 ]
Lu, Chang-Sheng [1 ]
Meng, Qing-Jin [1 ]
Zheng, Li-Min [1 ]
机构：
[1] Nanjing Univ, Sch Chem & Chem Engn, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
[2] Nanyang Inst Technol, Sch Biol & Chem Engn, Nanyang 473004, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2013年 / 28卷
关键词：
Lanthanide; Coordination polymer; Anthraquinone-1,4,5,8-tetracarboxylic acid; Hydrogen bond; METAL-ORGANIC FRAMEWORKS; GAS-ADSORPTION; CATALYSIS; POROSITY;
D O I：
10.1016/j.inoche.2012.11.012
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A series of isostructural two-dimensional lanthanide complexes with the formula [Ln(Haqtc)(H2O)(4)center dot xH(2)O](n) (Ln=Nd, 1; Sm, 2; Eu, 3; Tb, 4; Dy, 5; Er, 6.) were synthesized by treating H(4)aqtc (H(4)aqtc=anthraquinone-1,4,5,8-tetracarboxylic acid) with lanthanide(III) salts under hydrothermal conditions. 3-D structures are formed by inter-layer hydrogen bonds. Magnetic susceptibility measurements of complexes 4 and 5 in temperature range 2-300 K were performed, which showed dominant weak ferromagnetic interactions in 4 and slow magnetization relaxation in 5. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：20 / 24
页数：5
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