Gold Phenolate Complexes: Synthesis, Structure, and Reactivity

被引：46
|
作者：
Ibrahim, Nada [1 ]
Vilhelmsen, Mie Hojer [2 ]
Pernpointner, Markus [3 ]
Rominger, Frank [2 ]
Hashmi, A. Stephen K. [1 ,2 ]
机构：
[1] CaRLa Catalysis Res Lab, D-69120 Heidelberg, Germany
[2] Heidelberg Univ, Inst Organ Chem, D-69221 Heidelberg, Germany
[3] Heidelberg Univ, Inst Phys Chem, D-69120 Heidelberg, Germany
来源：
ORGANOMETALLICS | 2013年 / 32卷 / 09期
关键词：
BASIS-SETS; CARBENE; ATOMS; TRANSFORMATION; CATALYSIS; ALKOXIDES; HYDRATION; GROUP-11; BEARING;
D O I：
10.1021/om400060s
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Seven different NHC gold(I) phenolate complexes were synthesized. Structural data, including X-ray crystal structure analyses, could be obtained for each of them. An investigation by computational chemistry, including NBO analysis, indicates three-center-four-electron hyperbonds among the carbene carbon, the gold atom, and the oxygen atom of the phenolate with an approximate 60:40 distribution of the bonding interaction in favor of the carbene-gold bond. The new class of complexes shows only moderate catalytic activity.
引用
收藏
页码：2576 / 2583
页数：8
相关论文
共 50 条
  • [1] Synthesis, structure, and reactivity of novel ruthenium(II) phenolate complexes
    Kondo, T
    Tsunawaki, F
    Ura, Y
    Sadaoka, K
    Iwasa, T
    Wada, K
    Mitsudo, TA
    ORGANOMETALLICS, 2005, 24 (05) : 905 - 910
  • [2] Mesityl-vanadinm(III)-phenolate complexes:: Synthesis, structure, and reactivity
    Thiele, K
    Görls, H
    Imhof, W
    Seidel, W
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2002, 628 (01): : 107 - 118
  • [3] Gold(I) phosphido complexes: Synthesis, structure, and reactivity
    Stefanescu, DM
    Yuen, HF
    Glueck, DS
    Golen, JA
    Zakharov, LN
    Incarvito, CD
    Rheingold, AL
    INORGANIC CHEMISTRY, 2003, 42 (26) : 8891 - 8901
  • [4] Synthesis, Structure, and Reactivity of Gold(I) α-Oxo Carbenoid Complexes
    Stow, Caroline P.
    Widenhoefer, Ross A.
    ORGANOMETALLICS, 2020, 39 (08) : 1249 - 1257
  • [5] SYNTHESIS, STRUCTURE, PROPERTIES AND REACTIVITY OF LOW VALENT VANADIUM COMPLEXES INCORPORATING PHENOLATE AND CARBOXYLATE LIGANDS
    WILISCH, WCA
    SCOTT, MJ
    GELMINI, L
    ARMSTRONG, WH
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1990, 199 : 547 - INOR
  • [6] Diastereoselective synthesis, structure and reactivity studies of ferrocenyloxazoline gold(i) and gold(ii) complexes
    Holz, Julia
    Garcia, Marta Ayerbe
    Frey, Wolfgang
    Krupp, Felix
    Peters, Rene
    DALTON TRANSACTIONS, 2018, 47 (11) : 3880 - 3905
  • [7] Synthesis and structure of aluminium amine-phenolate complexes
    Johnson, Andrew L.
    Davidson, Matthew G.
    Perez, Yolanda
    Jones, Matthew D.
    Merle, Nicolas
    Raithby, Paul R.
    Richards, Stephen P.
    DALTON TRANSACTIONS, 2009, (28) : 5551 - 5558
  • [8] Synthesis, characterization and reactivity of heteroleptic rare earth metal bis(phenolate) complexes
    Qi, Ruipeng
    Liu, Bao
    Xu, Xiaoping
    Yang, Zijian
    Yao, Yingming
    Zhang, Yong
    Shen, Qi
    DALTON TRANSACTIONS, 2008, (37) : 5016 - 5024
  • [9] Chiral Diamine Bis(phenolate) TiIV and ZrIV Complexes - Synthesis, Structures and Reactivity
    Barroso, Sonia
    Adao, Pedro
    Duarte, M. Teresa
    Meetsma, Auke
    Pessoa, Joao Costa
    Bouwkamp, Marco W.
    Martins, Ana M.
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2011, (27) : 4277 - 4290
  • [10] Structure and reactivity of gold(III) terpyridine complexes
    Hardwick, Mark C.
    Gomez, Vivian
    Hahn, Christine
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 240
12345