Polymers of intrinsic microporosity as high temperature templates for the formation of nanofibrous oxides

被引:24
作者
Al Kutubi, H. [1 ,2 ]
Rassaei, L. [2 ]
Olthuis, W. [3 ]
Nelson, G. W. [4 ]
Foord, J. S. [5 ]
Holdway, P. [6 ]
Carta, M. [7 ]
Malpass-Evans, R. [7 ]
McKeown, N. B. [7 ]
Tsang, S. C. [8 ]
Castaing, R. [1 ]
Forder, T. R. [1 ]
Jones, M. D. [1 ]
He, D. [1 ]
Marken, F. [1 ]
机构
[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England
[2] Delft Univ Technol, Dept Chem Engn, Delft, Netherlands
[3] Univ Twente, CBIOS Lab On A Chip Grp, NL-7500 Enschede, Netherlands
[4] Univ London Imperial Coll Sci Technol & Med, Dept Mat, Royal Sch Mines, London SW7 2AZ, England
[5] Univ Oxford, Chem Res Labs, Oxford OX1 3TA, England
[6] Begbroke Sci Pk, Dept Mat, Oxford OX5 1PF, England
[7] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland
[8] Univ Oxford, Inorgan Chem Lab, Oxford OX1 3QR, England
关键词
DOPED INDIUM OXIDE; PRASEODYMIUM OXIDE; DEPOSITION; FILMS; PIMS;
D O I
10.1039/c5ra15131g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The highly rigid molecular structure of Polymers of Intrinsic Microporosity (PIM) - associated with a high thermolysis threshold - combined with the possibility to fill intrinsic micropores allows the direct "one-step" templated conversion of metal nitrates into nanostructured metal oxides. This is demonstrated here with PIM-EA-TB and with PIM-1 for the conversion of Pr(NO3)(3) to Pr6O11.
引用
收藏
页码:73323 / 73326
页数:4
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