Polymers of intrinsic microporosity as high temperature templates for the formation of nanofibrous oxides

被引:24
作者
Al Kutubi, H. [1 ,2 ]
Rassaei, L. [2 ]
Olthuis, W. [3 ]
Nelson, G. W. [4 ]
Foord, J. S. [5 ]
Holdway, P. [6 ]
Carta, M. [7 ]
Malpass-Evans, R. [7 ]
McKeown, N. B. [7 ]
Tsang, S. C. [8 ]
Castaing, R. [1 ]
Forder, T. R. [1 ]
Jones, M. D. [1 ]
He, D. [1 ]
Marken, F. [1 ]
机构
[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England
[2] Delft Univ Technol, Dept Chem Engn, Delft, Netherlands
[3] Univ Twente, CBIOS Lab On A Chip Grp, NL-7500 Enschede, Netherlands
[4] Univ London Imperial Coll Sci Technol & Med, Dept Mat, Royal Sch Mines, London SW7 2AZ, England
[5] Univ Oxford, Chem Res Labs, Oxford OX1 3TA, England
[6] Begbroke Sci Pk, Dept Mat, Oxford OX5 1PF, England
[7] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland
[8] Univ Oxford, Inorgan Chem Lab, Oxford OX1 3QR, England
关键词
DOPED INDIUM OXIDE; PRASEODYMIUM OXIDE; DEPOSITION; FILMS; PIMS;
D O I
10.1039/c5ra15131g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The highly rigid molecular structure of Polymers of Intrinsic Microporosity (PIM) - associated with a high thermolysis threshold - combined with the possibility to fill intrinsic micropores allows the direct "one-step" templated conversion of metal nitrates into nanostructured metal oxides. This is demonstrated here with PIM-EA-TB and with PIM-1 for the conversion of Pr(NO3)(3) to Pr6O11.
引用
收藏
页码:73323 / 73326
页数:4
相关论文
共 27 条
[1]   Growth of praseodymium oxide thin films by liquid injection MOCVD using a novel praseodymium alkoxide precursor [J].
Aspinall, HC ;
Gaskell, J ;
Williams, PA ;
Jones, AC ;
Chalker, PR ;
Marshall, PA ;
Bickley, JF ;
Smith, LM ;
Critchlow, GW .
CHEMICAL VAPOR DEPOSITION, 2003, 9 (05) :235-+
[2]   Nanostructured praseodymium oxide:: Preparation, structure, and catalytic properties [J].
Borchert, Yulia ;
Sonstroem, Patrick ;
Wilhelm, Michaela ;
Borchert, Holger ;
Baeumer, Marcus .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (08) :3054-3063
[3]   Nanostructure templating in inorganic solids with organic lyotropic liquid crystals [J].
Braun, PV ;
Osenar, P ;
Tohver, V ;
Kennedy, SB ;
Stupp, SI .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (32) :7302-7309
[4]   Gas separation membranes from polymers of intrinsic microporosity [J].
Budd, PM ;
Msayib, KJ ;
Tattershall, CE ;
Ghanem, BS ;
Reynolds, KJ ;
McKeown, NB ;
Fritsch, D .
JOURNAL OF MEMBRANE SCIENCE, 2005, 251 (1-2) :263-269
[5]   Polymers of intrinsic microporosity (PIMs): robust, solution-processable, organic nanoporous materials [J].
Budd, PM ;
Ghanem, BS ;
Makhseed, S ;
McKeown, NB ;
Msayib, KJ ;
Tattershall, CE .
CHEMICAL COMMUNICATIONS, 2004, (02) :230-231
[6]   Solution-processed, organophilic membrane derived from a polymer of intrinsic microporosity [J].
Budd, PM ;
Elabas, ES ;
Ghanem, BS ;
Makhseed, S ;
McKeown, NB ;
Msayib, KJ ;
Tattershall, CE ;
Wang, D .
ADVANCED MATERIALS, 2004, 16 (05) :456-+
[7]   An Efficient Polymer Molecular Sieve for Membrane Gas Separations [J].
Carta, Mariolino ;
Malpass-Evans, Richard ;
Croad, Matthew ;
Rogan, Yulia ;
Jansen, Johannes C. ;
Bernardo, Paola ;
Bazzarelli, Fabio ;
McKeown, Neil B. .
SCIENCE, 2013, 339 (6117) :303-307
[8]   Nanostructure fabrication using block copolymers [J].
Hamley, IW .
NANOTECHNOLOGY, 2003, 14 (10) :R39-R54
[9]   Atomistic packing model and free volume distribution of a polymer with intrinsic microporosity (PIM-1) [J].
Heuchel, Matthias ;
Fritsch, Detlev ;
Budd, Peter M. ;
McKeown, Neil B. ;
Hofmann, Dieter .
JOURNAL OF MEMBRANE SCIENCE, 2008, 318 (1-2) :84-99
[10]   Thermal genesis course and characterization of praseodymium oxide from praseodymium nitrate hydrate [J].
Hussein, GAM ;
Balboul, BAA ;
A-Warith, MA ;
Othman, AGM .
THERMOCHIMICA ACTA, 2001, 369 (1-2) :59-66