Control over Catenation in Pillared Paddlewheel Metal-Organic Framework Materials via Solvent-Assisted Linker Exchange

被引：126

作者：

Bury, Wojciech ^{[1
,2
,3
]}

Fairen-Jimenez, David ^{[4
,5
]}

Lalonde, Marianne B. ^{[1
,2
]}

Snurr, Randall Q. ^{[4
]}

Farha, Omar K. ^{[1
,2
]}

Hupp, Joseph T. ^{[1
,2
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

[2] Northwestern Univ, Int Inst Nanotechnol, Evanston, IL 60208 USA

[3] Warsaw Univ Technol, Dept Chem, PL-00664 Warsaw, Poland

[4] Northwestern Univ, Dept Chem & Biol Engn, Evanston, IL 60208 USA

[5] Univ Cambridge, Dept Chem Engn & Biotechnol, Cambridge CB2 3RA, England

来源：

CHEMISTRY OF MATERIALS | 2013年 / 25卷 / 05期

关键词：

catenation; metal-organic frameworks; SALE; linker exchange; POSTSYNTHETIC LIGAND; RATIONAL DESIGN; SURFACE-AREA; STRATEGY; INTERPENETRATION; PURIFICATION; POROSITY; STORAGE; SOLIDS; ROUTE;

D O I：

10.1021/cm303749m

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Control over catenation in a pillared paddlewheel metal-organic framework was achieved via solvent-assisted linker exchange. The linker exchange was demonstrated on the noncatenated structure of DO-MOF, by using 4,4'-bipyridine (L4) and 4,4'-azobis(pyridine) (L5) as linkers, leading to noncatenated materials SALEM-3 and SALEM-4. The de novo synthesized analogues of SALEM-3 and SALEM-4 can only be obtained as 2-fold interpenetrated frameworks. The reaction progress of the linker exchange was monitored by NMR spectroscopy, and structure and framework catenation were characterized by powder X-ray diffraction and thermogravimetric methods.

引用

页码：739 / 744

页数：6

共 55 条

[31] Metal-organic framework materials as catalysts [J].

Lee, JeongYong ;

Farha, Omar K. ;

Roberts, John ;

Scheidt, Karl A. ;

Nguyen, SonBinh T. ;

Hupp, Joseph T. .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1450-1459

[32] Selective gas adsorption and separation in metal-organic frameworks [J].

Li, Jian-Rong ;

Kuppler, Ryan J. ;

Zhou, Hong-Cai .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1477-1504

[33] Metal-Organic Frameworks as Sensors: A ZIF-8 Based Fabry-Perot Device as a Selective Sensor for Chemical Vapors and Gases [J].

Lu, Guang ;

Hupp, Joseph T. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (23) :7832-+

[34] A General Thermolabile Protecting Group Strategy for Organocatalytic Metal-Organic Frameworks [J].

Lun, David J. ;

Waterhouse, Geoffrey I. N. ;

Telfer, Shane G. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (15) :5806-5809

[35] Enantioselective catalysis with homochiral metal-organic frameworks [J].

Ma, Liqing ;

Abney, Carter ;

Lin, Wenbin .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1248-1256

[36] Framework-catenation isomerism in metal-organic frameworks and its impact on hydrogen uptake [J].

Ma, Shengqian ;

Sun, Daofeng ;

Ambrogio, Michael ;

Fillinger, Jacqueline A. ;

Parkin, Sean ;

Zhou, Hong-Cai .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (07) :1858-+

[37] A flexible interpenetrating coordination framework with a bimodal porous functionality [J].

Maji, Tapas Kumar ;

Matsuda, Ryotaro ;

Kitagawa, Susumu .

NATURE MATERIALS, 2007, 6 (02) :142-148

[38] Post-Synthesis Alkoxide Formation Within Metal-Organic Framework Materials: A Strategy for Incorporating Highly Coordinatively Unsaturated Metal Ions [J].

Mulfort, Karen L. ;

Farha, Omar K. ;

Stern, Charlotte L. ;

Sarjeant, Amy A. ;

Hupp, Joseph T. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (11) :3866-+

[39] Hydrogen storage in metal-organic frameworks [J].

Murray, Leslie J. ;

Dinca, Mircea ;

Long, Jeffrey R. .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1294-1314

[40] UFF, A FULL PERIODIC-TABLE FORCE-FIELD FOR MOLECULAR MECHANICS AND MOLECULAR-DYNAMICS SIMULATIONS [J].

RAPPE, AK ;

CASEWIT, CJ ;

COLWELL, KS ;

GODDARD, WA ;

SKIFF, WM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (25) :10024-10035

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