Crystal Growth of Cyclodextrin-based Metal-Organic Framework for Carbon Dioxide Capture and Separation

被引:23
作者
Yan, Ton Kar [1 ,2 ,3 ]
Nagai, Anna [1 ]
Michida, Wataru [1 ]
Kusakabe, Katsuki [1 ,2 ]
Yusup, Suzana Binti [3 ]
机构
[1] Sojo Univ, Dept Nanosci, Nishi Ku, 4-22-1 Ikeda, Kumamoto 8600082, Japan
[2] Kyushu Univ, Int Inst Carbon Neutral Energy Res WPI CNER I2, Nishi Ku, 744 Motooka, Fukuoka 8190395, Japan
[3] Univ Teknol Petronas, Dept Chem Engn, Tronoh 32610, Perak, Malaysia
来源
PROCEEDING OF 4TH INTERNATIONAL CONFERENCE ON PROCESS ENGINEERING AND ADVANCED MATERIALS (ICPEAM 2016) | 2016年 / 148卷
关键词
CD-MOF; CO2; adsorption; cyclodextrin; ADSORPTION; CO2;
D O I
10.1016/j.proeng.2016.06.480
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Crystalline cyclodextrin-based metal-organic framework (CD-MOF) was synthesized by vapor diffusion of methanol into a KOH solution of.-cyclodextrin (gamma-CD). Its CO2 adsorption behaviors were evaluated both qualitatively and quantitatively. The adsorption behaviors of CD-MOF to separate and capture CO2 have been tested by using thermogravimetric analysis in the multiple adsorption-desorption process. The chemical sorption of CO2 was found to be caused by the formation of reversible carbonic acid. The adsorption amount of CO2 was tested in pure CO2 gas and 25vol% CO2 in Ar gas. As a result, there is no difference of the adsorption amount against the CO2 concentration and the saturated adsorption amount was 24 mg-CO2/g-CD-MOF at 30 degrees C. (C) 2016 The Authors. Published by Elsevier Ltd.
引用
收藏
页码:30 / 34
页数:5
相关论文
共 10 条
  • [1] Separation of CO2 from CH4 using mixed-ligand metal-organic frameworks
    Bae, Youn-Sang
    Mulfort, Karen L.
    Frost, Houston
    Ryan, Patrick
    Punnathanam, Sudeep
    Broadbelt, Linda J.
    Hupp, Joseph T.
    Snurr, Randall Q.
    [J]. LANGMUIR, 2008, 24 (16) : 8592 - 8598
  • [2] Cheung O., 2014, Narrow-pore zeolites and zeolite-like adsorbents for co2 separation
  • [3] Nanoporous Carbohydrate Metal-Organic Frameworks
    Forgan, Ross S.
    Smaldone, Ronald A.
    Gassensmith, Jeremiah J.
    Furukawa, Hiroyasu
    Cordes, David B.
    Li, Qiaowei
    Wilmer, Christopher E.
    Botros, Youssry Y.
    Snurr, Randall Q.
    Slawin, Alexandra M. Z.
    Stoddart, J. Fraser
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (01) : 406 - 417
  • [4] Strong and Reversible Binding of Carbon Dioxide in a Green Metal-Organic Framework
    Gassensmith, Jeremiah J.
    Furukawa, Hiroyasu
    Smaldone, Ronald A.
    Forgan, Ross S.
    Botros, Youssry Y.
    Yaghi, Omar M.
    Stoddart, J. Fraser
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (39) : 15312 - 15315
  • [5] Application of thermogravimetry and differential scanning calorimetry for the evaluation of CO2 adsorption on chemically modified adsorbents
    Liu, Zhen-Shu
    Peng, Yu-Hui
    Huang, Chun-Yi
    Hung, Ming-Jui
    [J]. THERMOCHIMICA ACTA, 2015, 602 : 8 - 14
  • [6] Crystal growth of cyclodextrin-based metal-organic framework with inclusion of ferulic acid
    Michida, Wataru
    Ezaki, Masato
    Sakuragi, Mina
    Guan, Guoqing
    Kusakabe, Katsuki
    [J]. CRYSTAL RESEARCH AND TECHNOLOGY, 2015, 50 (07) : 556 - 559
  • [7] Smaldone R.A., ANGEW CHEM INT ED, V49, P8630
  • [8] Direct Calorimetric Measurement of Enthalpy of Adsorption of Carbon Dioxide on CD-MOF-2, a Green Metal-Organic Framework
    Wu, Di
    Gassensmith, Jeremiah J.
    Gouvea, Douglas
    Ushakov, Sergey
    Stoddart, J. Fraser
    Navrotsky, Alexandra
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (18) : 6790 - 6793
  • [9] A Review of CO2 Capture by Absorption and Adsorption
    Yu, Cheng-Hsiu
    Huang, Chih-Hung
    Tan, Chung-Sung
    [J]. AEROSOL AND AIR QUALITY RESEARCH, 2012, 12 (05) : 745 - 769
  • [10] Adsorption and Diffusion of Carbon Dioxide on Metal-Organic Framework (MOF-5)
    Zhao, Zhenxia
    Li, Zhong
    Lin, Y. S.
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2009, 48 (22) : 10015 - 10020