Determination of the atomic composition of isobaric ions in the mass-spectrometric study of the L-asparagine monohydrate

被引:5
|
作者
Vukstich, V. S. [1 ]
Romanova, L. G. [1 ]
Snegursky, A. V. [1 ]
机构
[1] Natl Acad Sci Ukraine, Inst Electron Phys, UA-88017 Uzhgorod, Ukraine
关键词
SINGLE-CRYSTALS; MOLECULE;
D O I
10.1134/S1063785012040153
中图分类号
O59 [应用物理学];
学科分类号
摘要
The mass spectrum of the L-asparagine monohydrate (C4H8N2O3 center dot H2O) ionized by the 70-eV electron impact has been studied within the = 10-50 amu mass range. A method for determining the most probable atomic composition of the products of fragmentation is suggested. The maximum error of determination of the mass of a fragment ion by this method did not exceed 0.04%. The molecular fragments were analyzed using a commercial MI-1201 mass spectrometer linked to an IBM PC with a digital system of mass spectrum sweep and data acquisition control.
引用
收藏
页码:347 / 350
页数:4
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