Mn4+ doped zero-dimensional organic-inorganic hybrid material with narrow-red emission

被引：26
作者：
Cai, Peiqing [1 ]
Wang, Song [1 ]
Xu, Tianmou [1 ]
Tang, Ying [1 ,2 ]
Yuan, Xiaolin [2 ]
Wan, Mingjie [1 ]
Ai, Qi [1 ]
Si, Junjie [1 ]
Yao, Xin [1 ]
Cao, Yonggang [3 ]
Rabchinskii, Maxim K. [4 ]
Brunkov, Pavel N. [4 ]
Liu, Zugang [1 ]
机构：
[1] China Jiliang Univ, Coll Opt & Elect Technol, Hangzhou 310018, Zhejiang, Peoples R China
[2] Ningbo Semicond Int Corp, Ningbo 315800, Zhejiang, Peoples R China
[3] China Jiliang Univ, Coll Metrol & Measurement Engn, Hangzhou 310018, Zhejiang, Peoples R China
[4] Ioffe Inst, 26 Politekhnicheskaya, St Petersburg 194021, Russia
来源：
JOURNAL OF LUMINESCENCE | 2020年 / 228卷
基金：
中国国家自然科学基金;
关键词：
Mn4+ doped phosphors; Organic-inorganic hybrid material; Narrow red emission; PHOTOLUMINESCENCE; EFFICIENT; PHOSPHORS; POLAR;
D O I：
10.1016/j.jlumin.2020.117661
中图分类号：
O43 [光学];
学科分类号：
070207 ; 0803 ;
摘要：
Recently, low-dimensional organic-inorganic hybrid halide compounds have aroused great attention in optoelectronic field, due to the unique topology and optical properties. Herein, we report a Mn4+ doped [N (CH3)(4)](2)TiF6 zero-dimensional organic-inorganic hybrid phosphor, which could not only exhibit very narrow and pure red emission, but also maintain efficient emission intensity at room temperature. The crystal structure, photoluminescence properties, and temperature sensing application are discussed. The temperature dependent luminescent properties are attributed to the rigid structure and isolated MnF62- octahedra in the total crystal framework. These results will help design suitable materials and devices in both warm white light emitting diodes and optical sensors.
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页数：7
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