Renner-Teller and spin-orbit interactions between the (A)over-tilde2A1 and the (X)over-tilde 2B1 states of NH2:: The stretch-bender approach

被引：11
|
作者：
Alijah, A
Duxbury, G
机构：
[1] Univ Bielefeld, Fak Chem, D-33615 Bielefeld, Germany
[2] Univ Strathclyde, Dept Phys & Appl Phys, Glasgow G4 0NG, Lanark, Scotland
来源：
JOURNAL OF MOLECULAR SPECTROSCOPY | 2002年 / 211卷 / 01期
基金：
英国工程与自然科学研究理事会;
关键词：
Renner-Teller; stretch-bender; electronic angular momentum; spin-orbit interaction; NH2;
D O I：
10.1006/jmsp.2001.8479
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
The stretch-bender model, developed originally to describe the effects of stretch-bend interactions and Renner-Teller coupling in symmetrical triatomic molecules, has been extended to incorporate the effects of spin-orbit interaction and of overall rotation. A comparison is made between the treatment of spin-orbit interaction and of overall rotation in our model and in the MORBID approach of P. Jensen, M. Brumm, W. P. Kraemer, and P.R. Bunker (C) 2002 Elsevier Science.
引用
收藏
页码：7 / 15
页数：9
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