Thermal stability of the heterofullerene (C59N)X for X=C59N,H.

被引：0

作者：

Plank, W ^{[1
]}

Pichler, T ^{[1
]}

Baes-Fischlmair, S ^{[1
]}

Krause, M ^{[1
]}

Kuzmany, H ^{[1
]}

Tagmatarchis, N ^{[1
]}

Shinohara, H ^{[1
]}

机构：

[1] Univ Vienna, Inst Mat Phys, A-01090 Vienna, Austria

来源：

ELECTRONIC PROPERTIES OF MOLECULAR NANOSTRUCTURES | 2001年 / 591卷

关键词：

D O I：

暂无

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The stability of the azafullerenes of the type (C59N)X was studied by using IR, mass spectroscopy, optical and Raman experiments. X represents either hydrogen or an other cage of C59N. Experimental data indicate thermal stability of the solid phase of the dieter up to 600 K followed by very slow degradation extending beyond 700 K. This is compared to our latest results on the temperature stability of C59HN which was found to be stable only up to 540 K. A sudden change in the spectra at this temperature gives evidence for a transition to a new air stable phase. Since the mass spectra show no loss of hydrogen the new Phase is claimed to be polymerized C59HN. When heated in vacuum to about 700 K this phase dimerizes into (C59N)(2).

引用

页码：16 / 19

页数：4

共 50 条

[21] On the crystal structure of azafullerene (C59N)(2)
Brown, CM
Cristofolini, L
Kordatos, K
Prassides, K
Bellavia, C
Gonzalez, R
KeshavarzK, M
Wudl, F
Cheetham, AK
Zhang, JP
Andreoni, W
Curioni, A
Fitch, AN
Pattison, P
CHEMISTRY OF MATERIALS, 1996, 8 (11) : 2548 - &
[22] C59N Monomers: Stabilization through Immobilization
School of Physics and Astronomy, University of Nottingham, Nottingham NG7 2RD, United Kingdom
不详
不详
不详
不详
不详
不详
Phys Rev Lett, 17 (3478-3481):
[23] Vibrational and electronic excitations of (C59N)2
Auerhammer, JM
Kim, T
Knupfer, M
Golden, MS
Fink, J
Tagmatarchis, N
Prassides, K
SOLID STATE COMMUNICATIONS, 2001, 117 (12) : 697 - 701
[24] Film Growth of C59N on layered materials
Pietzak, B
Sommerhalter, C
Weidinger, A
Nuber, B
Reuther, U
Hirsch, A
ELECTRONIC PROPERTIES OF NOVEL MATERIALS - PROGRESS IN MOLECULAR NANOSTRUCTURES: XII INTERNATIONAL WINTERSCHOOL, 1998, 442 : 223 - 226
[25] IMPURITY STATES IN DOPED FULLERENES - C59B AND C59N
ANDREONI, W
GYGI, F
PARRINELLO, M
CHEMICAL PHYSICS LETTERS, 1992, 190 (3-4) : 159 - 162
[26] Oscillations in the Valence-hand photoemission spectrum of the heterofullerene C59N:: A photoelectron interference phenomenon
Jones, FH
Butcher, MJ
Cotier, BN
Moriarty, P
Beton, PH
Dhanak, VR
Prassides, K
Kordatos, K
Tagmatarchis, N
Wudl, F
PHYSICAL REVIEW B, 1999, 59 (15): : 9834 - 9837
[27] In situ hydrogenation of C59N and resonant electron capture of C59NHx (x = 0, 1 and 5)
Vasil'ev, YV
Abzalimov, RR
Tuktarov, RF
Nasibullaev, SK
Hirsch, A
Taylor, R
Drewello, T
CHEMICAL PHYSICS LETTERS, 2002, 354 (5-6) : 361 - 366
[28] Chemisorption of azafullerene on silicon:: isolating C59N monomers
Butcher, MJ
Jones, FH
Cotier, BN
Taylor, MDR
Moriarty, P
Beton, PH
Prassides, K
Tagmatarchis, N
Comicioli, C
Ottaviani, C
Crotti, C
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2000, 74 (1-3): : 202 - 205
[29] C59N单分子整流器
王克东
李斌
杨金龙
侯建国
物理, 2006, (03) : 188 - 192
[30] Production of C59N:C60 solid solution
Fülöp, F
Rockenbauer, A
Simon, F
Pekker, S
Korecz, L
Garaj, S
Jánossy, A
NANONETWORK MATERIALS: FULLERENES, NANOTUBES AND RELATED SYSTEMS, 2001, 590 : 329 - 332

← 1 2 3 4 5 →