Aerobic oxidation of alkanes in the presence of acetaldehyde catalysed by copper-crown ether

被引：54

作者：

Komiya, N ^{[1
]}

Naota, T ^{[1
]}

Murahashi, SI ^{[1
]}

机构：

[1] OSAKA UNIV,FAC ENGN SCI,DEPT CHEM,TOYONAKA,OSAKA 560,JAPAN

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 10期

关键词：

D O I：

10.1016/0040-4039(96)00074-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Copper-crown ether catalysed oxidation of alkanes with molecular oxygen in the presence of acetaldehyde gives the corresponding ketones and alcohols highly efficiently. High turnover numbers have been obtained for the oxidations of cyclohexane using copper(II) chloride and 18-crown-6 as a catalyst.

引用

页码：1633 / 1636

页数：4

共 45 条

[41] Oxidation of (E,E,Z)-1,5,9-cyclododecatriene catalysed by palladium(II) acetate in the presence of copper(II) acetate and air:: A kinetic study
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JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 137 (1-3) : 77 - 83
[42] Copper salt-crown ether systems as catalysts for the oxidation of cumene with 1-methyl-1-phenylethylhydroperoxide to bis(1-methyl-1-phenylethyl)peroxide
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[45] F-ELEMENT CROWN ETHER COMPLEXES .10. OXIDATION OF UCL4 TO [UO2CL4]2- IN THE PRESENCE OF CROWN ETHERS - STRUCTURAL CHARACTERIZATION OF CROWN ETHER COMPLEXES AMMONIUM-IONS [(NH4)(15-CROWN-5)2]2[UO2CL4].2CH3CN, [(NH4)(BENZO-15-CROWN-5)2]2[UCL6].4CH3CN, AND [(NH4)(DIBENZO-18-CROWN-6)]2[UO2CL4].2CH3CN AND SYNTHESIS OF [NA(12-CROWN-4)2]2[UO2CL4].2OHME AND [UO2CL2(OH2)3].18-CROWN-6.H2O.OHMEB
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KURIHARA, LK
BENNING, MM
INORGANIC CHEMISTRY, 1987, 26 (26) : 4346 - 4352

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