Aerobic oxidation of alkanes in the presence of acetaldehyde catalysed by copper-crown ether

被引：54
|
作者：
Komiya, N [1 ]
Naota, T [1 ]
Murahashi, SI [1 ]
机构：
[1] OSAKA UNIV,FAC ENGN SCI,DEPT CHEM,TOYONAKA,OSAKA 560,JAPAN
来源：
TETRAHEDRON LETTERS | 1996年 / 37卷 / 10期
关键词：
D O I：
10.1016/0040-4039(96)00074-3
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Copper-crown ether catalysed oxidation of alkanes with molecular oxygen in the presence of acetaldehyde gives the corresponding ketones and alcohols highly efficiently. High turnover numbers have been obtained for the oxidations of cyclohexane using copper(II) chloride and 18-crown-6 as a catalyst.
引用
收藏
页码：1633 / 1636
页数：4
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