Investigation of FeB alloy prepared by an electric arc method and used as the anode material for alkaline secondary batteries

被引:36
作者
Bai, Ying [1 ]
Wu, Chuan [1 ]
Wu, Feng [1 ]
Yang, Li-xin [1 ]
Wu, Bo-rong [1 ]
机构
[1] Beijing Inst Technol, Sch Chem Engn & Environm, Beijing 100081, Peoples R China
基金
中国国家自然科学基金;
关键词
Alkaline secondary battery; Electric arc method; FeB alloy; Multi-electron reaction; Electrochemical performance; CO-B ALLOYS; HYDROGEN GENERATION; NABH4; SOLUTION; ELECTROCHEMICAL BEHAVIORS; CATALYSTS;
D O I
10.1016/j.elecom.2008.09.038
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
High active FeB alloy was prepared by an electric arc method, and used as the anode material for alkaline secondary batteries. The structural characteristics of the as-prepared FeB alloy were studied using X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS), and the electrochemical performances were investigated using cyclic voltammetry (CV) and charge-discharge test. The FeB alloy achieves an excellent reversible capacity of 312 mA h/g as well as a good cycleability, and is proved to be a promising low-cost and high performance anode material for alkaline secondary batteries. (c) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:145 / 148
页数:4
相关论文
共 15 条
  • [1] Properties of iron boride films prepared by magnetron sputtering
    Dehlinger, AS
    Pierson, JF
    Roman, A
    Bauer, P
    [J]. SURFACE & COATINGS TECHNOLOGY, 2003, 174 : 331 - 337
  • [2] *JCPDS, 320463 JCPDS
  • [3] A structured Co-B catalyst for hydrogen extraction from NaBH4 solution
    Lee, Jaeyoung
    Kong, Kyung Yong
    Jung, Chang Ryul
    Cho, Eunae
    Yoon, Sung Pil
    Han, Jonghee
    Lee, Tai-Gyu
    Nam, Suk Woo
    [J]. CATALYSIS TODAY, 2007, 120 (3-4) : 305 - 310
  • [4] Liquid phase hydrogenation of acetonitrile to ethylamine over the Co-B amorphous alloy catalyst
    Li, HX
    Wu, YD
    Luo, HS
    Wang, MG
    Xu, YP
    [J]. JOURNAL OF CATALYSIS, 2003, 214 (01) : 15 - 25
  • [5] Structure and electrochemical behaviors of a series of Co-B alloys
    Liu, Yi
    Wang, Yijing
    Xiao, Lingling
    Song, Dawei
    Wang, Yaping
    Jiao, Lifang
    Yuan, Huatang
    [J]. ELECTROCHIMICA ACTA, 2008, 53 (05) : 2265 - 2271
  • [6] Oxidation and deprotonation of synthetic FeII-FeIII (oxy)hydroxycarbonate Green Rust:: An X-ray photoelectron study
    Mullet, M.
    Guillemin, Y.
    Ruby, C.
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 2008, 181 (01) : 81 - 89
  • [7] Pierson JF, 2004, SURF COAT TECH, V180, P44, DOI 10.1016/j.surfcoat.2003.10.032
  • [8] Exceptional electrochemical activities of amorphous Fe-B and Co-B alloy powders used as high capacity anode materials
    Wang, YD
    Ai, XP
    Cao, YL
    Yang, HX
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2004, 6 (08) : 780 - 784
  • [9] Cobalt boride catalysts for hydrogen generation from alkaline NaBH4 solution
    Wu, C
    Wu, F
    Bai, Y
    Yi, BL
    Zhang, HM
    [J]. MATERIALS LETTERS, 2005, 59 (14-15) : 1748 - 1751
  • [10] Fast hydrogen generation from NaBH4 solution accelerated by ferric catalysts
    Wu, Chuan
    Bai, Ying
    Wu, Feng
    [J]. MATERIALS LETTERS, 2008, 62 (27) : 4242 - 4244