Observation of solid-state 103Rh NMR by cross-polarization

被引：10

作者：

Phillips, BL ^{[1
]}

Houston, JR

Feng, J

Casey, WH

机构：

[1] SUNY Stony Brook, Ctr Environm Mol Sci, Dept Geosci, Stony Brook, NY 11794 USA

[2] SUNY Stony Brook, Ctr Environm Mol Sci, Dept Chem, Stony Brook, NY 11794 USA

[3] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 12期

关键词：

D O I：

10.1021/ja057347s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Using 103Rh[1H] cross-polarization (CP) methods, we have obtained solid-state 103Rh NMR spectra for diamagnetic Rh(III) compounds. The isotropic chemical shift and chemical shift anisotropy (CSA) are reported for a crystalline form of the dihydroxy-bridged Rh(III) dimer and for a salt of the oxo-centered acetate-bridged Rh(III) trimer, from analysis of conventional CP/MAS spectra. Comparison of the CP kinetics of the dimer with new crystal structure data suggests a strategy for predicting 103Rh CP/MAS properties in solids. Copyright © 2006 American Chemical Society.

引用

页码：3912 / 3913

页数：2

共 19 条

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