PCBs and PAHs in sea-surface microlayer and sub-surface water samples of the Venice Lagoon (Italy)

被引：77
作者：
Manodori, L
Gambaro, A [1 ]
Piazza, R
Ferrari, S
Stortini, AM
Moret, I
Capodaglio, G
机构：
[1] Univ Venice, Dept Environm Sci, I-30123 Venice, Italy
[2] CNR, Inst Dynam Environm Proc, I-30123 Venice, Italy
[3] CNR, Inst Atmospher Sci & Climate, I-40129 Bologna, Italy
来源：
MARINE POLLUTION BULLETIN | 2006年 / 52卷 / 02期
关键词：
GC-MS; sea-surface microlayer; PAHs; PCBs; pollution; sub-surface water; Venice Lagoon;
D O I：
10.1016/j.marpolbul.2005.08.017
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
Polychlorinated biphenyls (PCBs) and polycyclic aromatic hydrocarbons (PAHs) are two classes of micropollutants intensively monitored and regulated due to their toxicity, persistency and wide diffusion. Their concentrations have been investigated in sea-microlayer (SML) and sub-surface water (SSW) samples collected at two sites of the Venice Lagoon, a fragile ecosystem highly influenced by industrial and anthropogenic emissions. The total Sigma PCB concentration varies from 0.45 ng/l to 2.1 ng/l in SSW while a clear enrichment is observed in the SML, where it ranges from 1.2 ng/l to 10.5 ng/l. The total Sigma PAH concentration shows marked differences between the two stations and varies from 12.4 ng/l to 266.8 ng/l in SSW; in SML it is more uniform and ranges from 19.6 ng/l to 178.9 ng/l. The enrichment factors are not larger than I for both pollutants in the 'dissolved' phase, while they are most significant for the 'particulate' phase (EPCB: 5-9; Sigma PAH: 4-14). (c) 2005 Elsevier Ltd. All rights reserved.
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收藏
页码：184 / 192
页数：9
相关论文
共 27 条
[11]   THE SEA-SURFACE MICROLAYER OF PUGET SOUND .2. CONCENTRATIONS OF CONTAMINANTS AND RELATION TO TOXICITY [J].
HARDY, JT ;
CRECELIUS, EA ;
ANTRIM, LD ;
BROADHURST, VL ;
APTS, CW ;
GURTISEN, JM ;
FORTMAN, TJ .
MARINE ENVIRONMENTAL RESEARCH, 1987, 23 (04) :251-271
[12]   Persistent organic pollutants (POPs): state of the science [J].
Jones, KC ;
de Voogt, P .
ENVIRONMENTAL POLLUTION, 1999, 100 (1-3) :209-221
[13]   ORGANIC CONTAMINANTS IN WINYAH BAY, SOUTH-CAROLINA .1. PESTICIDES AND POLYCYCLIC AROMATIC-HYDROCARBONS IN SUBSURFACE AND MICROLAYER WATERS [J].
KUCKLICK, JR ;
BIDLEMAN, TF .
MARINE ENVIRONMENTAL RESEARCH, 1994, 37 (01) :63-78
[14]   Selecting chemical substances for the UN-ECE POP protocol [J].
Lerche, D ;
van de Plassche, E ;
Schwegler, A ;
Balk, F .
CHEMOSPHERE, 2002, 47 (06) :617-630
[15]   Surface microlayer enrichment of polycyclic aromatic hydrocarbons in Southern Chesapeake Bay [J].
Liu, KW ;
Dickhut, RM .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1997, 31 (10) :2777-2781
[16]   Determination of polychlorobiphenyl congeners (PCBs) in the surface water of the Venice lagoon [J].
Moret, I ;
Gambaro, A ;
Piazza, R ;
Ferrari, S ;
Manodori, L .
MARINE POLLUTION BULLETIN, 2005, 50 (02) :167-174
[17]   INFLOW, LEVELS AND THE FATE OF SOME PERSISTENT CHLORINATED HYDROCARBONS IN THE RIJEKA BAY AREA OF THE ADRIATIC SEA [J].
PICER, N ;
PICER, M .
WATER RESEARCH, 1992, 26 (07) :899-909
[18]   CONCENTRATIONS OF CHLORINATED PESTICIDES AND PCBS IN MICROLAYER AND SEAWATER SAMPLES COLLECTED IN OPEN-OCEAN WATERS OFF THE UNITED-STATES EAST COAST AND IN THE GULF OF MEXICO [J].
SAUER, TC ;
DURELL, GS ;
BROWN, JS ;
REDFORD, D ;
BOEHM, PD .
MARINE CHEMISTRY, 1989, 27 (3-4) :235-257
[19]   THE FATE OF TOXIC AIRBORNE POLLUTANTS [J].
SCHROEDER, WH ;
LANE, DA .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1988, 22 (03) :240-246
[20]   The changing state of contamination in the Lagoon of Venice. Part 1: organic pollutants [J].
Secco, T ;
Pellizzato, F ;
Sfriso, A ;
Pavoni, B .
CHEMOSPHERE, 2005, 58 (03) :279-290
123