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A Schiff base compound as effective corrosion inhibitor for magnesium in acidic media
被引:77
作者:
Seifzadeh, D.
[1
]
Basharnavaz, H.
[1
]
Bezaatpour, A.
[2
]
机构:
[1] Univ Mohaghegh Ardabili, Phys Chem Res Lab, Dept Appl Chem, Fac Sci, Ardebil, Iran
[2] Univ Mohaghegh Ardabili, Inorgan Chem Res Lab, Dept Appl Chem, Fac Sci, Ardebil, Iran
关键词:
Corrosion;
Electrochemical techniques;
Adsorption;
SEM;
IMPEDANCE PLANE DISPLAYS;
MILD-STEEL CORROSION;
STABILITY CONDITIONS;
STEADY-STATE;
ALUMINUM;
EFFICIENCY;
SILICATE;
CHLORIDE;
ALLOY;
D O I:
10.1016/j.matchemphys.2012.12.063
中图分类号:
T [工业技术];
学科分类号:
08 ;
摘要:
The inhibition effect of a Schiff base compound (Salcn) on magnesium corrosion was studied using potentiodynamic polarization, EIS (Electrochemical Impedance Spectroscopy) and EN (Electrochemical Noise) methods. It was found that this compound acts as a strong inhibitor for magnesium in 0.01 M HCl. Results showed that this compound acts as a mixed type inhibitor. As the inhibitor concentration increased, the corrosion resistance of magnesium increased. The results of EN measurements in frequency domain were in good agreement with other methods results. It was also found that this inhibitor mainly acts through physical adsorption on the metal surface. Also, adsorption obeys the Freundlich isotherm. SEM (Scanning Electron Microscopy) images revealed that the damage of magnesium surface has diminished in the presence of inhibitor. (C) 2013 Elsevier B.V. All rights reserved.
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页码:794 / 802
页数:9
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