Synthesis of 1,2,4-oxadiazolidines via [3+2] cycloaddition of nitrones with carbodiimides

被引：6

作者：

Chen, Yuan ^{[1
]}

Fuyue, Liuting ^{[1
]}

Wang, Gangqiang ^{[1
]}

Wang, Hang ^{[1
]}

Lu, Chun ^{[1
]}

Guo, Haibing ^{[1
]}

St Amant, Chiara ^{[2
]}

Sun, Shaofa ^{[1
]}

Xing, Yalan ^{[2
]}

机构：

[1] Hubei Univ Sci & Technol, Sch Nucl Technol & Chem & Biol, Nonpower Nucl Technol Collaborat Innovat Ctr, Xianning 437100, Peoples R China

[2] William Paterson Univ New Jersey, Dept Chem, 300 Pompton Rd, Wayne, NJ 07470 USA

来源：

NEW JOURNAL OF CHEMISTRY | 2019年 / 43卷 / 11期

关键词：

AZA-OXYALLYLIC CATIONS;

D O I：

10.1039/c9nj00030e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient [3+2] cycloaddition of nitrones and carbodiimides has been developed. This 1,3-dipolar cycloaddition features high regioselectivity, mild and metal-free conditions, excellent functional group compatibility, and a broad substrate scope. The X-ray structures of two regio-isomers confirmed the regioselectivity of this transformation.

引用

页码：4329 / 4332

页数：4