The use of sulfonyl halides as initiators of cationic polymerization of oxazolines

被引：9
|
作者：
Kurlykin, M. P. [1 ]
Razina, A. B. [1 ]
Ten'kovtsev, A. V. [1 ,2 ]
机构：
[1] Russian Acad Sci, Inst Macromol Cpds, St Petersburg 199004, Russia
[2] St Petersburg State Univ, Inst Chem, St Petersburg 198504, Russia
来源：
POLYMER SCIENCE SERIES B | 2015年 / 57卷 / 05期
基金：
俄罗斯科学基金会;
关键词：
2-PHENYL-2-OXAZOLINE; 2-ETHYL-2-OXAZOLINE; 2-OXAZOLINES;
D O I：
10.1134/S1560090415050085
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The kinetic investigations of the cationic polymerization of 2-ethyl-2-oxazoline are performed with the use of aromatic sulfonic acid halides as initiators. The rate constants of chain propagation and the activation energy are calculated. It is found that the polymerization predominantly proceeds via the livingchain, rather than the pseudoliving, polymerization mechanism.
引用
收藏
页码：395 / 401
页数：7
相关论文
共 50 条
  • [41] Metal catalyzed ''living'' radical polymerization initiated with sulfonyl halides.
    Percec, V
    Barboiu, B
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1997, 213 : 500 - POLY
  • [42] Iodonium Borate Initiators for Cationic Photopolymerization and Their Application in Radical-Induced Cationic Frontal Polymerization
    Taschner, Roland
    Liska, Robert
    Knaack, Patrick
    ACS APPLIED POLYMER MATERIALS, 2022, 4 (10) : 7878 - 7890
  • [43] Sulfonyl chlorides as initiators for the ruthenium-mediated living radical polymerization of methyl methacrylate
    Matsuyama, M
    Kamigaito, M
    Sawamoto, M
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1996, 34 (17) : 3585 - 3589
  • [44] Microwave Effects Due to Anionic or Cationic Initiators in Emulsion Polymerization Reactions
    Costa, Cristiane
    Santos, Verusca H. S.
    Sayer, Claudia
    Araujo, Pedro H. H.
    Santos, Alexandre F.
    Fortuny, Montserrat
    POLYMER REACTION ENGINEERING - 10TH INTERNATIONAL WORKSHOP, 2011, 302 : 161 - 168
  • [45] Aromatic acetals as new initiators for cationic polymerization of isobutyl vinyl ether
    Satoh, K
    Kamigaito, M
    Sawamoto, M
    MACROMOLECULES, 2000, 33 (03) : 748 - 753
  • [46] Polymerization of 2-oxazolines via cationic and enzymatic catalysis to functional polymers
    Kobayashi, Shiro
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
  • [47] REGIOSELECTIVE POLYMERIZATION OF VINYL KETENE CYCLIC ACETAL BY MEANS OF CATIONIC INITIATORS
    FUKUDA, H
    ODA, M
    ENDO, T
    MACROMOLECULAR RAPID COMMUNICATIONS, 1994, 15 (07) : 579 - 585
  • [48] DEVELOPMENTS IN THE DESIGN AND APPLICATIONS OF NOVEL THERMAL AND PHOTOCHEMICAL INITIATORS FOR CATIONIC POLYMERIZATION
    CRIVELLO, JV
    LEE, JL
    CONLON, DA
    MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1988, 13-4 : 145 - 160
  • [49] Sulfonyl chlorides as initiators for the Ruthenium-mediated living radical polymerization of methyl methacrylate
    Matsuyama, Mutsuhiro
    Kamigaito, Masami
    Sawamoto, Mitsuo
    1996, John Wiley & Sons Inc, New York, NY, United States (34)
  • [50] CATIONIC POLYMERIZATION OF TETRAHYDROFURAN INITIATED BY DIFUNCTIONAL INITIATORS - SYNTHESIS OF BLOCK COPOLYMERS
    HAZER, B
    EUROPEAN POLYMER JOURNAL, 1990, 26 (11) : 1167 - 1170
12345