Structure-property relationship of homochiral and achiral supramolecular isomers obtained by one-pot synthesis

被引：50

作者：

Qin, Ling ^{[1
]}

Hu, Jin-Song ^{[1
]}

Zhang, Ming-Dao ^{[1
]}

Guo, Zi-Jian ^{[1
]}

Zheng, He-Gen ^{[1
]}

机构：

[1] Nanjing Univ, Natl Lab Microstruct, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 87期

关键词：

METAL-ORGANIC FRAMEWORKS; SINGLE-MOLECULE MAGNETS; COORDINATION POLYMERS; ASYMMETRIC CATALYSIS; SOLID-STATE; CRYSTALLIZATION; ADSORPTION; COMPLEXES; NETWORKS; CLUSTERS;

D O I：

10.1039/c2cc36003a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two supramolecular isomers, {[Co(L)(OBA)]center dot H2O}(n) (1), {[Co5O2(L)(2)(OBA)(3)]center dot 7DMF}(n) (2), have been synthesized by one-pot reactions. Compound 1 has a homochiral architecture with low connectivity, and compound 2 is an achiral 3D framework with high 12-connectivity. It is unprecedent to get homochiral and achiral supramolecular isomers by one-pot synthesis.

引用

页码：10757 / 10759

页数：3

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