Structure-property relationship of homochiral and achiral supramolecular isomers obtained by one-pot synthesis

被引：50
|
作者：
Qin, Ling [1 ]
Hu, Jin-Song [1 ]
Zhang, Ming-Dao [1 ]
Guo, Zi-Jian [1 ]
Zheng, He-Gen [1 ]
机构：
[1] Nanjing Univ, Natl Lab Microstruct, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 87期
关键词：
METAL-ORGANIC FRAMEWORKS; SINGLE-MOLECULE MAGNETS; COORDINATION POLYMERS; ASYMMETRIC CATALYSIS; SOLID-STATE; CRYSTALLIZATION; ADSORPTION; COMPLEXES; NETWORKS; CLUSTERS;
D O I：
10.1039/c2cc36003a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two supramolecular isomers, {[Co(L)(OBA)]center dot H2O}(n) (1), {[Co5O2(L)(2)(OBA)(3)]center dot 7DMF}(n) (2), have been synthesized by one-pot reactions. Compound 1 has a homochiral architecture with low connectivity, and compound 2 is an achiral 3D framework with high 12-connectivity. It is unprecedent to get homochiral and achiral supramolecular isomers by one-pot synthesis.
引用
收藏
页码：10757 / 10759
页数：3
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