The Construction of a 3D Pr(III) Coordination Polymer Based on 2-Methyl Imidazole-4,5-dicarboxylate and Oxalate Ligands

被引：4
作者：
Chen, Nan [1 ]
Wang, Chengjie [1 ]
Guo, Mengwei [1 ]
Gao, Yongchao [1 ]
Li, Gang [1 ]
机构：
[1] Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Henan, Peoples R China
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2012年 / 42卷 / 07期
基金：
中国国家自然科学基金;
关键词：
crystal structure; imidazole dicarboxylate; polymer Pr(III); properties; LANTHANIDE-ORGANIC FRAMEWORK; STRUCTURAL-CHARACTERIZATION; CRYSTAL-STRUCTURE; HELICAL CHAINS; COMPLEXES; LUMINESCENCE; CONTRACTION; SERIES; ACID;
D O I：
10.1080/15533174.2012.680132
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Solvothermal reaction of Pr(NO3)(3)center dot 6H(2)O with 2-methyl-1H-imidazole- 4,5-dicarboxylic acid (H3MIDC) and ammonium oxalate affords a metal-organic framework, {[Pr-2(mu(3)-HMIDC)(2)(mu(2)-C2O4)(H2O)(3)]center dot EtOH center dot 3H(2)O}(n) (1), which has been structurally characterized by single-crystal X-ray diffraction. Polymer 1 exhibits a novel 3D structure, in which infinite 1D chains, composed of nine-coordinated Pr(III) ions and oxalates, were linked by mu(3)-HMIDC2- to give rise to a 3D architecture. Its thermal and solid-state fluorescence properties have been investigated.
引用
收藏
页码：981 / 986
页数：6
相关论文
共 42 条
[31]   Porous lanthanide-organic open frameworks with helical tubes constructed from interweaving triple-helical and double-helical chains [J].
Sun, YQ ;
Zhang, J ;
Chen, YM ;
Yang, GY .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (36) :5814-5817
[32]   A Series of Three-Dimensional Lanthanide-Rigid-Flexible Frameworks: Synthesis, Structure, and Luminescent Properties of Coordination Polymers with 2,5-Pyridine Dicarboxylic Acid and Adipic Acid [J].
Wang, Chun-Guang ;
Xing, Yong-Heng ;
Li, Zhang-Peng ;
Li, Jing ;
Zeng, Xiao-Qing ;
Ge, Mao-Fa ;
Niu, Shu-Yun .
CRYSTAL GROWTH & DESIGN, 2009, 9 (03) :1525-1530
[33]   From Metal-Organic Squares to Porous Zeolite-like Supramolecular Assemblies [J].
Wang, Shuang ;
Zhao, Tingting ;
Li, Guanghua ;
Wojtas, Lukasz ;
Huo, Qisheng ;
Eddaoudi, Mohamed ;
Liu, Yunling .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (51) :18038-18041
[34]   2-Phenyl-4,5-imidazole dicarboxylate-based metal-organic frameworks assembled under hydro(solvo)thermal conditions [J].
Wang, Wen-Yue ;
Yang, Ze-Li ;
Wang, Cheng-Jie ;
Lu, Hui-Jie ;
Zang, Shuang-Quan ;
Li, Gang .
CRYSTENGCOMM, 2011, 13 (15) :4895-4902
[35]   One Chiral and Two Achiral 3-D Coordination Polymers Constructed by 2-Phenyl Imidazole Dicarboxylate [J].
Wang, Wenyue ;
Niu, Xiling ;
Gao, Yongchao ;
Zhu, Yanyan ;
Li, Gang ;
Lu, Huijie ;
Tang, Mingsheng .
CRYSTAL GROWTH & DESIGN, 2010, 10 (09) :4050-4059
[36]   Synthesis, crystal structure, and luminescence of a new coordination polymer, {[Cd9(IDC)2(HIDC)6(Bipy)4] • 2N(CH3)(CH2CH3)2 • 2DMF}n [J].
Yang, Kun ;
Wang, Zhuan-Zhuan ;
Liu, Zhi-Hong .
JOURNAL OF COORDINATION CHEMISTRY, 2010, 63 (13) :2286-2295
[37]   A series of novel chiral lanthanide coordination polymers with channels constructed from 16Ln-based cage-like building units [J].
Yuan, Gang ;
Shao, Kui-Zhan ;
Wang, Xin-Long ;
Lan, Ya-Qian ;
Du, Dong-Ying ;
Su, Zhong-Min .
CRYSTENGCOMM, 2010, 12 (04) :1147-1152
[38]   Four Novel Frameworks Built by Imidazole-Based Dicarboxylate Ligands: Hydro(Solvo)thermal Synthesis, Crystal Structures, and Properties [J].
Zhang, Fuwei ;
Li, Zifeng ;
Ge, Tiezhu ;
Yao, Hongchang ;
Li, Gang ;
Lu, Huijie ;
Zhu, Yanyan .
INORGANIC CHEMISTRY, 2010, 49 (08) :3776-3788
[39]   Three new complexes synthesized from an imidazole-based dicarboxylate ligand containing hydroxymethyl group [J].
Zheng, Sheng-Run ;
Cai, Song-Liang ;
Fan, Jun ;
Xiao, Tian-Tian ;
Zhang, Wei-Guang .
INORGANIC CHEMISTRY COMMUNICATIONS, 2011, 14 (07) :1097-1101
[40]   Two novel porous luminescent lanthanide-organic frameworks with new four-nodal (3,4)-connected network topology [J].
Zheng, Sheng-Run ;
Cai, Song-Liang ;
Yang, Qing-Yuan ;
Xiao, Tian-Tian ;
Fan, Jun ;
Zhang, Wei-Guang .
INORGANIC CHEMISTRY COMMUNICATIONS, 2011, 14 (06) :826-830
12345