Stability investigations of electrocatalysts on the nanoscale

被引:229
作者
Meier, Josef C. [1 ]
Katsounaros, Ioannis [1 ]
Galeano, Carolina [2 ]
Bongard, Hans J. [2 ]
Topalov, Angel A. [1 ,3 ]
Kostka, Aleksander [4 ]
Karschin, Arndt [1 ]
Schueth, Ferdi [2 ]
Mayrhofer, Karl J. J. [1 ]
机构
[1] Max Planck Inst Eisenforsch GmbH, Dept Interface Chem & Surface Engn, D-40237 Dusseldorf, Germany
[2] Max Planck Inst Kohlenforsch, Dept Heterogeneous Catalysis, D-45470 Mulheim, Germany
[3] Ruhr Univ Bochum, Ctr Electrochem Sci, D-44780 Bochum, Germany
[4] Max Planck Inst Eisenforsch GmbH, Dept Microstruct Phys & Alloy Design, D-40237 Dusseldorf, Germany
关键词
TRANSMISSION ELECTRON-MICROSCOPY; OXYGEN REDUCTION REACTION; MEMBRANE FUEL-CELLS; CATALYST DEGRADATION; PHOSPHORIC-ACID; DISK ELECTRODE; CORROSION; NANOPARTICLES; INSTABILITY; TEM;
D O I
10.1039/c2ee22550f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The search for more stable electrocatalyst materials for electrochemical energy conversion requires a fundamental understanding of the underlying degradation processes. Advanced characterization techniques like identical location transmission electron microscopy (IL-TEM) can provide invaluable insight into the stability of electrode materials on the nanoscale. In this review, the basic principles and the methodology of IL-TEM are described, and its capabilities are revealed by demonstrating the recent progress that has been achieved in research on the stability of fuel cell catalysts. Moreover, we provide future perspectives of the identical location approach towards implementing other electron microscopic and tomographic applications, which will help us to gain an even broader view of the degradation of electrocatalysts.
引用
收藏
页码:9319 / 9330
页数:12
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