Grafting of 1-Cyanoethanoyl-4-acryloylthiosemicabazide onto Chitosan and Biocidal Activity of the Graft Copolymers

被引：5
作者：
Elkholy, Said S. [1 ]
Khalek, Hend. A. [1 ]
Elsabee, Maher Z. [1 ]
机构：
[1] Cairo Univ, Dept Chem, Fac Sci, Cairo 12613, Egypt
来源：
JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY | 2012年 / 49卷 / 09期
关键词：
Chitosan; 1-Cyanoethanoyl-4-acryloylthiosemicabazide; graft copolymer; swelling behavior; biological activity; DERIVATIVES; 4-VINYLPYRIDINE; CHITIN;
D O I：
10.1080/10601325.2012.703495
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Chitosan was grafted with a novel monomer 1-Cyanoethanoyl-4-acryloylthiosemicabazide (CEATS). The graft copolymerization was conducted using potassium persulfate (K2S2O8) and sodium bisulfite (NaHSO3) as redox initiators. The grafted samples were characterized by FTIR spectroscopy, scanning electron microscopy, X-ray diffraction, and thermogravimetric analysis. The data may indicate that grafting has occurred at the surface of chitosan. The grafted samples showed high water swelling. The antifungal behavior of chitosan and its graft copolymers was investigated in vitro and it has been found that grafting with CEATS noticeably enhances the antifungal activity.
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收藏
页码：720 / 728
页数：9
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