Nanostructured, Molecularly Imprinted, and Template-Patterned Polythiophenes for Chiral Sensing and Differentiation

被引:30
作者
Pernites, Roderick B. [3 ]
Venkata, Subrahmanyam K. [1 ,2 ]
Tiu, Brylee David B. [1 ,2 ]
Yago, Allan Christopher C. [1 ,2 ]
Advincula, Rigoberto C. [4 ]
机构
[1] Univ Houston, Dept Chem, Houston, TX 77204 USA
[2] Univ Houston, Dept Chem & Biomol Engn, Houston, TX 77204 USA
[3] Rice Univ, Dept Chem & Biomol Engn, Houston, TX 77005 USA
[4] Case Western Reserve Univ, Dept Macromol Sci & Engn, Cleveland, OH 44106 USA
基金
美国国家科学基金会;
关键词
molecular imprinting; sensor; colloidal templating; quartz crystal microbalance; electropolymerization; polythiophenes; POLYMERS; CHROMATOGRAPHY; BINDING;
D O I
10.1002/smll.201102331
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An innovation to thin-film molecular imprinting is presented for the sensitive detection and effective discrimination of chiral compounds using a portable quartz crystal microbalance transduction technique. The facile approach involves i) colloidal sphere layering of latex particles onto the surface via a Langmuir-Blodgett-like technique followed by ii) template molecular imprinting using electrodeposition of a single functional and cross-linking monomer. © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:1669 / 1674
页数:6
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