Is the simplest chemical reaction really so simple?

被引：44

作者：

Jankunas, Justin ^{[1
]}

Sneha, Mahima ^{[1
]}

Zare, Richard N. ^{[1
]}

Bouakline, Foudhil ^{[2
]}

Althorpe, Stuart C. ^{[3
]}

Herraez-Aguilar, Diego ^{[4
]}

Javier Aoiz, F. ^{[4
]}

机构：

[1] Stanford Univ, Dept Chem, Stanford, CA 94305 USA

[2] Max Born Inst, D-12489 Berlin, Germany

[3] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

[4] Univ Complutense Madrid, Fac Quim, Dept Quim Fis, E-28040 Madrid, Spain

来源：

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA | 2014年 / 111卷 / 01期

基金：

英国工程与自然科学研究理事会; 美国国家科学基金会;

关键词：

reaction dynamics; differential cross-sections; DYNAMICS;

D O I：

10.1073/pnas.1315725111

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Modern computational methods have become so powerful for predicting the outcome for the H + H-2 -> H-2 + H bimolecular exchange reaction that it might seem further experiments are not needed. Nevertheless, experiments have led the way to cause theorists to look more deeply into this simplest of all chemical reactions. The findings are less simple.

引用

收藏

页码：15 / 20

页数：6

相关论文

共 16 条

[1] Observation and interpretation of a time-delayed mechanism in the hydrogen exchange reaction [J].

Althorpe, SC ;

Fernández-Alonso, F ;

Bean, BD ;

Ayers, JD ;

Pomerantz, AE ;

Zare, RN ;

Wrede, E .

NATURE, 2002, 416 (6876) :67-70

[2] The H+H2 reactive system.: Progress in the study of the dynamics of the simplest reaction [J].

Aoiz, FJ ;

Bañares, L ;

Herrero, VJ .

INTERNATIONAL REVIEWS IN PHYSICAL CHEMISTRY, 2005, 24 (01) :119-190

[3] Differential cross sections for H + D2 → HD(v′=2, j′=0,3,6,9) + D at center-of-mass collision energies of 1.25, 1.61, and 1.97 eV [J].

Bartlett, Nate C. -M. ;

Jankunas, Justin ;

Goswami, Tapas ;

Zare, Richard N. ;

Bouakline, Foudhil ;

Althorpe, Stuart C. .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2011, 13 (18) :8175-8179

[4]

Bouakline F, 2009, SPRINGER SER CHEM PH, V97, P201

[5]

Brouard M, 2010, TUTORIALS IN MOLECULAR REACTION DYNAMICS, P1

[6] Differential cross sections for H+D2→HD (v′=2, J′=0,3,5)+D at 1.55 eV [J].

Fernández-Alonso, F ;

Bean, BD ;

Zare, RN .

JOURNAL OF CHEMICAL PHYSICS, 1999, 111 (06) :2490-2498

[7] Vibrational excitation through tug-of-war inelastic collisions [J].

Greaves, Stuart J. ;

Wrede, Eckart ;

Goldberg, Noah T. ;

Zhang, Jianyang ;

Miller, Daniel J. ;

Zare, Richard N. .

NATURE, 2008, 454 (7200) :88-91

[8] New, unexpected, and dominant mechanisms in the hydrogen exchange reaction [J].

Greaves, Stuart J. ;

Murdock, Daniel ;

Wrede, Eckart ;

Althorpe, Stuart C. .

JOURNAL OF CHEMICAL PHYSICS, 2008, 128 (16)

[9] Disagreement between theory and experiment grows with increasing rotational excitation of HD(v′, j′) product for the H + D2 reaction [J].

Jankunas, Justin ;

Sneha, Mahima ;

Zare, Richard N. ;

Bouakline, Foudhil ;

Althorpe, Stuart C. .

JOURNAL OF CHEMICAL PHYSICS, 2013, 138 (09)

[10] Seemingly Anomalous Angular Distributions in H+D2 Reactive Scattering [J].

Jankunas, Justin ;

Zare, Richard N. ;

Bouakline, Foudhil ;

Althorpe, Stuart C. ;

Herraez-Aguilar, Diego ;

Aoiz, F. Javier .

SCIENCE, 2012, 336 (6089) :1687-1690