Facile carbon-carbon bond cleavage in an (eta(3)-cyclooctenyl)cobalt complex exhibiting agostic C...H...Co bonding

被引：16
作者：
Cracknell, RB
Nicholls, JC
Spencer, JL
机构：
[1] UNIV SALFORD, SCI RES INST, DIV CHEM SCI, SALFORD M5 4WT, LANCS, ENGLAND
[2] UNIV BRISTOL, SCH CHEM, BRISTOL BS8 1TS, AVON, ENGLAND
来源：
ORGANOMETALLICS | 1996年 / 15卷 / 01期
关键词：
D O I：
10.1021/om950727+
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of [(eta(5)-C(5)Me(5))Co(eta(4)-1,5-cyclooctadiene)] with HBF4 . Me(2)O affords, at room temperature, an agostic eta(3)-cyclooctenyl complex which undergoes a facile ring opening to afford anti-[(eta(5)-C(5)Me(5))Co(eta(5)-1-propylpentadienyl)]BF4.
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收藏
页码：446 / 448
页数：3
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