Bis(eta(5)-cyclopentadienyl)bis(formato-O)titanium

被引：9

作者：

Gibson, DH ^{[1
]}

Ding, Y ^{[1
]}

Richardson, JF ^{[1
]}

Mashuta, MS ^{[1
]}

机构：

[1] UNIV LOUISVILLE,CTR CHEM CATALYSIS,LOUISVILLE,KY 40292

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270196002715

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, [Ti(C5H5)(2)(CHO2)(2)], has a 'bent metallocene' structure type typically found for Cp(2)MXY complexes. The Ti-O-C bond angles are larger than in related titanocene alkoxy complexes, suggesting enhanced rr character in the Ti-O bonds of the title compound; however, the Ti-O bond lengths are longer than those in related alkoxy compounds.

引用

页码：1614 / 1616

页数：3

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